73766-54-8Relevant articles and documents
Stereoselective Synthesis of Alcohols, III Stereochemistry of the Sigmatropic Rearrangement of (1-Cycloalkenylmethyl) Sulfoxides
Hoffmann, Reinhard W.,Goldmann, Siegfried,Gerlach, Rainer,Maak, Norbert
, p. 845 - 855 (2007/10/02)
Rearrangement of the chiral allyl sulfoxides 17 and 20 proceeded via the exo-transition state 14 to give the α-methylenecycloalkanols 18 and 21 in high enantiomeric purity.The extent of chirality transferred was less (44 and 60percent) on rearrangement of