737767-18-9

Basic information

• Product Name: (E)-1-(2-chloro-1-methylvinyl)-2-(methoxymethoxy)benzene
• Synonyms: (E)-1-(2-chloro-1-methylvinyl)-2-(methoxymethoxy)benzene
• CAS NO: 737767-18-9
• Molecular Weight: 212.676
• Mol File: 737767-18-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-1-(2-chloro-1-methylvinyl)-2-(methoxymethoxy)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-(2-chloro-1-methylvinyl)-2-(methoxymethoxy)benzene(737767-18-9)
• EPA Substance Registry System: (E)-1-(2-chloro-1-methylvinyl)-2-(methoxymethoxy)benzene(737767-18-9)

Safety Data

• Hazardous Substances Data: 737767-18-9(Hazardous Substances Data)

Upstream product

• 67-66-3 chloroform 
• 6515-18-0 1-[2-(methoxymethoxy)phenyl]ethanone 

Downstream Products

• 21535-97-7 3-methyl-benzofuran 
• 737767-20-3 (E)-2-(2-chloro-1-methylvinyl)phenol 

Relevant articles and documents

Theoretical and experimental study on the in-plane SN2-type substitution reaction of haloalkenes with inversion of configuration at the sp2 carbon

(Equation Presented) The intramolecular in-plane SN2 type reaction of haloalkene E-8a was predicted to be a facile process for the first time by DFT calculations (B3LYP/6-31+G(d),SCRF(dipole, solvent = DMF)) (ΔG = 14.4 kcal/mol). The prediction was confirmed experimentally. When E-8a was treated with NaH in DMF, benzofuran was obtained in 95% yield. On the other hand, Z-8a was recovered quantitatively even after heating at 110 °C.