7378-50-9Relevant articles and documents
Effects of substituent and solvent on the UV absorption energy of 4,4′-disubstituted stilbenes
Cao, Chenzhong,Chen, Guanfan,Wu, Yaxin
scheme or table, p. 1735 - 1744 (2012/05/05)
Twenty five samples of 4,4′-disubstituted stilbene derivatives were synthesized, and their UV absorption max wavelengths were determined in over 10 kinds of solvents including cyclohexane, ether, chloroform, acetonitrile and ethanol, in which 242 experimental data were recorded. The effects of substituents and solvents on the energy of their UV absorption max wavelengths were discussed. The research results showed: the energy of UV absorption max wavelengths of 4,4′-disubstituted stilbenes was mainly affected by their intramolecular structure (substituent effect) in a given solvent, that is, the energy is dominated by both of excited-state substituent parameter σ CC ex and polar substituent constant σ p. While their energy was dominated by the substituent effect and solvent effect in different kinds of solvents. An equation quantifying the energy of UV absorption max wavelengths of 4,4′-disubstituted stilbenes was developed. In addition, it is found that the n-octanol/water partition coefficient (logP) is more effective than the solvatochromic dye (E T(30)) in scaling the solvent effect. The equation employed the parameter logP has a better correlation and more specific physical meaning. Further, the energies of UV absorption max wavelengths of some reported compounds were predicted by the obtained equation, which are in agreement with their experimental values.
Spectroscopic Correlations between Supermolecules and Molecules. Anatomy of the Ion-Modulated Electronic Properties of the Nitrogen Donor in Monoazacrown-Derived Intrinsic Fluoroionophores
Yang, Jye-Shane,Hwang, Chung-Yu,Hsieh, Chia-Chun,Chiou, Shih-Yi
, p. 719 - 726 (2007/10/03)
The synthesis, absorption and emission spectra, fluorescence quantum yields, and fluorescence lifetimes of three compound series of trans-4,4′-disubstituted aminostilbenes (1-3) are reported. The chromo-/fluoroionophoric behavior of the monoaza-15-crown-5
Electronic Structure and Free-Energy Relationships for Some 4'-Substituted 4-Dimethylamino trans-Stilbenes by U.V. Photoelectron Spectroscopy
Cauletti, C.,Furlani, C.,Palma, A.,Piancastelli, M. N.,Schleinitz, K. D.,Gloyna, D.
, p. 829 - 836 (2007/10/02)
A series of 4'-substituted 4-dimethylamino trans-stilbenes 1-5 was investigated by UPS, in connection with conjugated donor-acceptor substituted double bond photochemistry.The measured and assigned spectra indicate a high sensitivity, depending on the changed electronic structure by 4'-substituents of compounds 1-5.Correlation of ionization energies in LFE-relationship with Hammett's ?p-values and other ground state data was proved, demonstrating UPS a powerful tool for substituent effect studies in conjugated double bond systems.