73790-20-2Relevant articles and documents
Fused-ring acceptors based on quinoxaline unit for highly efficient single-junction organic solar cells with low charge recombination
Chen, Yang,Fan, Jian,Huang, Yuting,Li, Yaowen,Sun, Bangjin
, (2021/07/21)
Two non-fullerene small molecule acceptors (TFQ-F and TFQ-Cl) based on quinoxaline unit were designed and synthesized for efficient organic solar cells (OSCs). These two acceptors showed intense absorption up to 900 nm and high thermal stabilities with decomposition temperatures over 360 °C due to their fused-ring skeletons. TFQ-F and TFQ-Cl are the A-D-A′-D-A type acceptors (A/A′ for acceptor unit and D for donor unit). TFQ-F and TFQ-Cl have the same D-A′-D fragment, which was flanked with different ending groups. The effect of different ending groups on their photophysical properties, electrochemical behaviors, micro-structures and charge recombination properties of active layers, and device performance were investigated systematically. PM6 with the complementary absorption to the two acceptors was used as the donor material. The pristine PM6:TFQ-F blend films displayed the optimal morphologies as revealed by AFM and TEM measurement. Organic solar cells based on PM6:TFQ-Cl blend film showed high JSC of 25.19 mA/cm2 and PCE of 13.2%. The Voc, JSC and PCE for PM6:TFQ-F film based device were 0.857 V, 23.70 mA/cm2 and 13.51%, respectively. The dependence of VOC/JSC on various light intensities indicated that PM6:TFQ-F/Cl based device had low charge recombination.
Phosphorus(III)-Mediated, Tandem Deoxygenative Geminal Chlorofluorination of 1,2-Diketones
Choi, Garam,Chung, Won-Jin,Hwang, Sunjoo,Jang, Hanna,Kim, Ha Eun
supporting information, p. 4190 - 4195 (2020/06/27)
Tetrasubstituted carbon containing two different halogen substituents was constructed in a single-step operation by utilizing the carbene-like reactivity of dioxaphospholene through the tandem reaction of electrophilic and nucleophilic halogenating reagents. It was crucial to devise non-dealkylatable phosphoramidite, which enabled the efficient formation of geminal chlorofluorides from various 1,2-diketones with (PhSO2)2NF and n-Bu4NCl. In addition, selective functionalization of the chlorine substituent was demonstrated, and the absence of halogen scrambling was confirmed.
Synthetic method and application of diphenylglyoxal compound
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Paragraph 0020-0022, (2019/11/20)
The invention provides a preparation method of a synthetic diphenylglyoxal compound. A methylbenzene compound is oxidized by oxygen under the co-catalysis action of cuprous bromide, sodium nitrite, DDQ and protonic acid, and the diphenylglyoxal compound is prepared by a one-step method. Through suitable selectivity and collaboration of a catalyst and a reaction condition, a target product with high yield is realized, the efficiency is high in the preparation process, the cost is low, very outstanding technical significance and application value are achieved in the field of medical intermediatesynthesis, and market prospects are wide.