73829-33-1Relevant articles and documents
Z-Selective Synthesis of Homoallylic Alcohols via 2-Alkenylation of Aldehydes by 1-(Tributylstannyl)-2-alkene
Miyake, Hideyoshi,Yamamura, Kimiaki
, p. 897 - 900 (2007/10/02)
1-(Tributylstannyl)-2-alkene reacts with a solution of an aldehyde and BuSnCl3 to give (Z)-homoallylic alcohol.Z-Selective 2-methyl-2-butenylation can be accomplished by using (Z)-2-methyl-1-(tributylstannyl)-2-butene instead of 1-(tributylstannyl)-2-alkene.This reaction is useful as a new method to make (Z)-double bond.An application ot the present method for a synthesis of pheromones is also described.