73864-45-6

Basic information

• Product Name: cyclohexyl-2,3,6-tridesoxy-4-O-p-nitrobnezoyl-3-(trifluoroacetamido)-β-L-ribo-hexopyranoside
• CAS NO: 73864-45-6
• Molecular Weight: 474.434
• Mol File: 73864-45-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: cyclohexyl-2,3,6-tridesoxy-4-O-p-nitrobnezoyl-3-(trifluoroacetamido)-β-L-ribo-hexopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: cyclohexyl-2,3,6-tridesoxy-4-O-p-nitrobnezoyl-3-(trifluoroacetamido)-β-L-ribo-hexopyranoside(73864-45-6)
• EPA Substance Registry System: cyclohexyl-2,3,6-tridesoxy-4-O-p-nitrobnezoyl-3-(trifluoroacetamido)-β-L-ribo-hexopyranoside(73864-45-6)

Safety Data

• Hazardous Substances Data: 73864-45-6(Hazardous Substances Data)

Upstream product

• 34820-21-8 1,5-anhydro-3,4-di-O-benzoyl-2,6-didesoxy-L-arabino-hex-1-enitol 
• 14218-08-7 2,3,4-tri-O-benzoyl-α-L-rhamnopyranosyl bromide 
• 73891-06-2 2,3,6-tridesoxy-3-(trifluoroacetamido)-L-ribo-hex-1-enitol 
• 73864-37-6 3-amino-1,5-anhydro-2,3,6-tridesoxy-L-ribo-hex-1-enitol 
• 122-04-3 4-nitro-benzoyl chloride 
• 73891-07-3 2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-(trifluoroacetamido)-L-ribo-hex-1-enitol 
• 108-93-0 cyclohexanol 

Relevant articles and documents

SUBSTITUTIONS D'ESTERS ALLYLIQUES: PREPARATION DE GLYCALS AMINES EN C-3 ET ETUDE DE LEUR GLYCOSIDATION ACIDO-CATALYSEE. APPLICATION A L'HEMISYNTHESE DE GLYCOSIDES DU GROUPE DES ANTHRACYCLINES

3-Amino-1,5-anhydro-2,3,6-trideoxy-L-arabino- and -L-ribo-hex-1-enitol were prepared by substitution of the allylic ester function of 1,5-anhydro-3,4-di-O-benzoyl-2,6-dideoxy-L-arabino-hex-1-enitol with sodium azide, followed by reduction with lithium aluminium hydride.Glycosidation was performed with various alcohols, in particular daunomycinone.In the latter case, the partial synthesis of 4'-epi- and 3',4'-epi-daunorubicines was accomplished in three major steps.