73896-07-8

Basic information

• Product Name: mesityleneacetyl chloride
• Synonyms: mesityleneacetyl chloride
• CAS NO: 73896-07-8
• Molecular Weight: 196.677
• Mol File: 73896-07-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: mesityleneacetyl chloride(CAS DataBase Reference)
• NIST Chemistry Reference: mesityleneacetyl chloride(73896-07-8)
• EPA Substance Registry System: mesityleneacetyl chloride(73896-07-8)

Safety Data

• Hazardous Substances Data: 73896-07-8(Hazardous Substances Data)

Upstream product

• 42287-87-6 3-(3,5-dimethylphenyl)propanoic acid 

Downstream Products

• 129009-78-5 N-2,4,6-trimethylphenylacetylproline 

Relevant articles and documents

Visible-Light Induced C(sp2)?H Amidation with an Aryl–Alkyl σ-Bond Relocation via Redox-Neutral Radical–Polar Crossover

We report an approach for the intramolecular C(sp2)?H amidation of N-acyloxyamides under photoredox conditions to produce δ-benzolactams with an aryl-alkyl σ-bond relocation. Computational studies on the designed reductive single electron transfer strategy led us to identify N-[3,5-bis(trifluoromethyl)benzoyl] group as the most effective amidyl radical precursor. Upon the formation of an azaspirocyclic radical intermediate by the selective ipso-addition with outcompeting an ortho-attack, radical–polar crossover was then rationalized to lead to the rearomative ring-expansion with preferential C?C bond migration.