739-33-3

Basic information

• Product Name: ethyl 4-{[(4-methylphenyl)sulfonyl]amino}benzoate
• Synonyms: benzoic acid, 4-[[(4-methylphenyl)sulfonyl]amino]-, ethyl ester
• CAS NO: 739-33-3
• Molecular Formula: C₁₆H₁₇NO₄S
• Molecular Weight: 319.3755
• Mol File: 739-33-3.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 468.5°C at 760 mmHg
• Flash Point: 237.2°C
• Density: 1.281g/cm³
• Vapor Pressure: 5.94E-09mmHg at 25°C
• Refractive Index: 1.591
• CAS DataBase Reference: ethyl 4-{[(4-methylphenyl)sulfonyl]amino}benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 4-{[(4-methylphenyl)sulfonyl]amino}benzoate(739-33-3)
• EPA Substance Registry System: ethyl 4-{[(4-methylphenyl)sulfonyl]amino}benzoate(739-33-3)

Safety Data

• Hazardous Substances Data: 739-33-3(Hazardous Substances Data)

Upstream product

• 98-59-9 p-toluenesulfonyl chloride 
• 94-09-7 p-aminoethylbenzoate 
• 51934-41-9 4-iodobenzoic acid ethyl ester 
• 70-55-3 toluene-4-sulfonamide 
• 1305205-38-2 C₁₉H₂₁NO₂S 
• 32848-24-1 ethyl 4-(((nonafluorobutyl)sulfonyl)oxy)benzoate 
• 17159-79-4 ethyl 4-oxocyclohexane-1-carboxylate 
• 98-09-9 benzenesulfonyl chloride 
• 5798-75-4 Ethyl 4-bromobenzoate 

Downstream Products

• 5411-30-3 4-[oxiranylmethyl-(toluene-4-sulfonyl)-amino]-benzoic acid ethyl ester 
• 100840-57-1 ethyl 4-<<(4-methylphenyl)sulfonyl>(4-phthalimidobutyl)amino>benzoate 
• 38064-59-4 4-(4-methylphenyl-sulfonamido)benzohydrazide 
• 5433-15-8 4-[(3,3-diethoxy-2-hydroxy-propyl)-(toluene-4-sulfonyl)-amino]-benzoic acid ethyl ester 
• 100840-74-2 ethyl 4-<(4-aminobutyl)amino>benzoate dihydrobromide 
• 100840-95-7 ethyl 4-<(4-aminobutyl)tosylamino>benzoate 
• 126632-44-8 4-<(5-cyano-6-ethoxy-6-oxohexyl)tosylamino>benzoate 
• 126632-45-9 4-<<4-(2,4-diamino-1,6-dihydro-6-oxo-5-pyrimidinyl)butyl>tosylamino>benzoic acid 
• 126632-46-0 diethyl N-<4-<<4-(2,4-diamino-1,6-dihydro-6-oxo-5-pyrimidinyl)butyl>tosylamino>benzoyl>-L-glutamate 
• 126632-31-3 N-<4-<<4-(2,4-diamino-1,6-dihydro-6-oxo-5-pyrimidinyl)butyl>amino>benzoyl>-L-glutamic acid 
• 1207865-34-6 C₂₂H₂₉NO₅S 
• 1207865-48-2 C₁₈H₁₉NO₄S 

Relevant articles and documents

Organic semiconductor photocatalyst can bifunctionalize arenes and heteroarenes

Photoexcited electron-hole pairs on a semiconductor surface can engage in redox reactions with two different substrates. Similar to conventional electrosynthesis, the primary redox intermediates afford only separate oxidized and reduced products or, more rarely, combine to one addition product. Here, we report that a stable organic semiconductor material, mesoporous graphitic carbon nitride (mpg-CN), can act as a visible-light photoredox catalyst to orchestrate oxidative and reductive interfacial electron transfers to two different substrates in a two- or three-component system for direct twofold carbon–hydrogen functionalization of arenes and heteroarenes. The mpg-CN catalyst tolerates reactive radicals and strong nucleophiles, is straightforwardly recoverable by simple centrifugation of reaction mixtures, and is reusable for at least four catalytic transformations with conserved activity.

Palladium-Catalyzed Allylic Amination of Homoallylic Alcohols with Amines via Carbon-Carbon Bond Cleavage

An efficient approach for palladium(II) acetate catalyzed allylic amination of homoallylic alcohols with various amines via sequential retro-allylation and amination was developed, which afforded the corresponding allylic amines in up to 98% yield.

Chemoselective nitration of aromatic sulfonamides with tert-butyl nitrite

A methodology for the efficient conversion of aromatic sulfonamides into their mono-nitro derivatives using tert-butyl nitrite is reported. The reaction exhibits a high degree of chemoselectivity for sulfonamide functionalized aryl systems, even in the presence of other sensitive or potentially reactive functionalities.