73945-57-0Relevant articles and documents
Influence de la taille du cycle sur la substitution electrophile des cycloalkyltrimethylsilanes. Synthese de cycloalkyldimethylfluorosilanes
Grignon-Dubois, M.,Dunogues, J.,Calas, R.
, p. 291 - 295 (2007/10/02)
Cycloalkyltrimethylsilanes, excepting cyclopropyl-, react with electrophiles by Si - Me bond splitting.Consequently silicon can be functionalized by this route.We also propose a new synthesis of cycloalkyldimethylfluoro(or chloro-)silanes.In the case of five or six member ring derivates, the observed results are interpreted by a mechanism involving initial abstraction of hydride ion from the silicon substrate.
