740-80-7Relevant articles and documents
Palladium-Catalyzed Aerobic Oxidative Carbonylation of Amines Enables the Synthesis of Unsymmetrical N,N′-Disubstituted Ureas
Zeng, Honglan,Du, Hongyan,Gong, Xu,Zhang, Jie,Han, Wei
, p. 1223 - 1226 (2021/06/02)
A ligand-free palladium-catalyzed aerobic oxidative carbonylation of amines for the synthesis of ureas, particular unsymmetrically N,N′-disubstituted ureas, which cannot be accessed by any other palladium-catalyzed oxidative carbonylation of amines to date, is presented. An array of symmetrical and unsymmetrical ureas were straightforwardly synthesized by using inexpensive, readily available, stable, and safe amines with good to excellent yields under a pressure of 1 atm. This novel method employs oxygen as the sole oxidant and offers an attractive alternative to transition-metal-based oxidant systems.
153. Azimine. VII. Herstellung durch Oxydation von Triazanen
Egger, Notker,Hoesch, Lienhard,Dreiding, Andre S.
, p. 1599 - 1607 (2007/10/02)
A novel method for the preparation of certain azimines 4 by oxidation of 1,2,3-trisubstituted triazanes 3 is described.Treatment of 3-aryl-triazane-1,2-diesters 3a-3c with lead tetraacetate afforded the 3-aryl-azimine-1,2-diesters 4a-4c.The precursor tria