74015-58-0Relevant articles and documents
Palladium(0)-catalyzed isomerization of α,β-epoxy ketones to β-diketones
Suzuki, M.,Watanabe, A.,Noyori, R.
, p. 230 - 236 (1988)
In the presence of catalytic amounts of tetrakis(triphenylphosphine)palladium(0) and 1,2-bis(diphenylphosphino)ethane, α,β-epoxy ketones isomerize to the corresponding β-diketones in high yields.Both open-chain and cyclic substrates can be used.Possible reaction mechanisms are discussed.
Palladium(0)-Catalyzed Reaction of α,β-Epoxy Ketones Leading to β-Diketones
Suzuki, M.,Watanabe, A.,Noyori, R.
, p. 2095 - 2096 (2007/10/02)
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