7404-40-2

Basic information

• Product Name: D-altro-2-heptulose phenylosazone
• CAS NO: 7404-40-2
• Molecular Weight: 388.423
• Mol File: 7404-40-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: D-altro-2-heptulose phenylosazone(CAS DataBase Reference)
• NIST Chemistry Reference: D-altro-2-heptulose phenylosazone(7404-40-2)
• EPA Substance Registry System: D-altro-2-heptulose phenylosazone(7404-40-2)

Safety Data

• Hazardous Substances Data: 7404-40-2(Hazardous Substances Data)

Upstream product

• 3019-74-7 sedoheptulose 
• 100-63-0 phenylhydrazine 
• 73364-67-7 D-galacto-heptulose phenylosazone 
• 5329-51-1 D-gluco-heptulose phenylosazone 
• 3624-30-4 L-gluco-[2]heptosulose-bis-phenylhydrazone 
• 488-38-0 D-glycero-D-gluco-heptitol 
• 488-38-0 (2R,3R,4R,5S,6S)-Heptane-1,2,3,4,5,6,7-heptaol 
• 4297-17-0 L-gluco-[2]heptulose 
• 72358-76-0 phenylhydrazine acetate 

Downstream Products

• 3624-30-4 DL-gluco-[2]heptosulose-bis-phenylhydrazone 
• 3624-30-4 DL-galacto-[2]heptosulose-bis-phenylhydrazone 
• 7510-98-7 L-(1R)-1-(2-phenyl-2H-[1,2,3]triazol-4-yl)-xylitol 
• 100-63-0 phenylhydrazine 
• 21090-79-9 3,6-anhydro-D-gluco-hept-2-ulose phenylosazone 
• 21090-79-9 3,6-anhydro-D-manno-hept-2-ulose phenylosazone 
• 81713-49-7 3,7-anhydro-D-gluco-hept-2-ulose phenylosazone 
• 74134-94-4 4-(β-D-arabinofuranosyl)-2-phenyl-1,2,3-osotriazole 
• 74134-95-5 4-α-D-arabinofuranosyl-2-phenyl-1,2,3-osotriazole 
• 81748-29-0 4-β-D-arabinopyranosyl-2-phenyl-1,2,3-osotriazole 
• 81748-28-9 4-(α-D-arabinopyranosyl)-2-phenyl-2H-1,2,3-triazole 
• 21090-79-9 3,6-anhydro-D-allo-2-heptulose phenylosazone 
• 21090-79-9 3,6-anhydro-D-altro-2-heptulose phenylosazone 
• 21090-79-9 3,6-anhydro-D-galacto-2-heptulose phenylosazone 

Relevant articles and documents

STRUCTURE AND ANOMERIC CONFIGURATION OF THE 3,6-ANHYDRO-OSAZONE DERIVATIVES OBTAINED FROM D-altro-2-HEPTULOSE PHENYLOSAZONE

Dehydration of D-altro-2-heptulose phenylosazone with methanolic sulfuric acid afforded two 3,6-anhydro-osazone derivatives (2 and 3).Compound 3 was obtained as the preponderant isomer, with inversion at C-1 (C-3 of the starting osazone), and 2 was obtained without inversion.Refluxing of 3 with copper sulfate afforded the C-nucleoside analog, namely, 2-phenyl-4-β-D-ribofuranosyl-1,2,3-osotriazole (4).Acetylation of 4 afforded the tri-O-acetyl derivative 5.The anomeric configuration was determined by c.d. and n.m.r. spectroscopy.The mass spectra of compounds 2-5 are discussed.