74065-63-7

Basic information

• Product Name: 6,6′-bis(hydroxymethyl)-2,2′-bipyridine
• Synonyms: 6,6′-bis(hydroxymethyl)-2,2′-bipyridine
• CAS NO: 74065-63-7
• Molecular Weight: 216.239
• Mol File: 74065-63-7.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: 6,6′-bis(hydroxymethyl)-2,2′-bipyridine(CAS DataBase Reference)
• NIST Chemistry Reference: 6,6′-bis(hydroxymethyl)-2,2′-bipyridine(74065-63-7)
• EPA Substance Registry System: 6,6′-bis(hydroxymethyl)-2,2′-bipyridine(74065-63-7)

Safety Data

• Hazardous Substances Data: 74065-63-7(Hazardous Substances Data)

Usage

General Description

6,6′-bis(hydroxymethyl)-2,2′-bipyridine is a chemical compound with the molecular formula C14H14N2O2. It consists of a bipyridine core with hydroxymethyl groups attached to the 6 and 6′ positions. 6,6′-bis(hydroxymethyl)-2,2′-bipyridine is commonly used as a ligand in coordination chemistry, where it can form stable complexes with metal ions. It has been studied for its potential applications in catalysis, fluorescence sensing, and as a building block for supramolecular assemblies. Additionally, it can be utilized in the synthesis of coordination polymers and other functional materials. Overall, 6,6′-bis(hydroxymethyl)-2,2′-bipyridine is a versatile chemical with diverse applications in the field of chemical research and material science.

Upstream product

• 142593-07-5 dimethyl 2,2'-bipyridine-6,6'-dicarboxylate 
• 40473-07-2 6-bromo-2-methoxypyridine 
• 34160-40-2 6-bromo-2-pyridinecarbaldehyde 
• 109-04-6 2-bromo-pyridine 
• 150058-63-2 2-bromo-6-({[dimethyl(2-methyl-2-propanyl)silyl]oxy}methyl)pyridine 
• 4479-74-7 2,2'-bipyridine-6,6'-dicarboxylic acid 
• 65739-40-4 6,6′-bis(ethoxycarbonyl)-2,2′-bipyridine 
• 4411-83-0 2,2′-bipyridine-6,6′-dicarbonitrile 
• 7275-43-6 [2,2']bipyridinyl 1,1'-dioxide 
• 366-18-7 [2,2]bipyridinyl 
• 82740-66-7 6,6'-dimethyl-2,2'-bipyridine 1,1'-di-N-oxide 
• 4411-80-7 6,6'-dimethyl-2,2'-bipyridine 
• 5315-25-3 2-bromo-6-methylpyridine 
• 33674-96-3 2-bromo-6-(hydroxymethyl)pyridine 

Downstream Products

• 96517-97-4 6,6'-bis-(bromomethyl)-2,2'-bipyridine 
• 49669-26-3 2,2'-bipyridine-6,6'-dicarbaldehyde 
• 74065-64-8 6,6'-di(chloromethyl)-2,2'-bipyridine 
• 123074-73-7 6-(hydroxymethyl)-6'-(bromomethyl)-2,2'-dipyridine 

Relevant articles and documents

A catalytic palladium active-metal template pathway to [2]rotaxanes

(Chemical Equation Presented) A multitasking template: [2]Rotaxanes have been synthesized with the help of a palladium active-metal template, which acts as both a template for threading and a catalyst for covalent-bond formation (see scheme). The synthesi

Phosphonate-Mediated Immobilization of Rhodium/Bipyridine Hydrogenation Catalysts

RhL2 complexes of phosphonate-derivatized 2,2′-bipyridine (bpy) ligands L were immobilized on titanium oxide particles generated in situ. Depending on the structure of the bipy ligand—number of tethers (1 or 2) to which the phosphonate end groups are attached and their location on the 2,2′-bipyridine backbone (4,4′-, 5,5′-, or 6,6′-positions)—the resulting supported catalysts showed comparable chemoselectivity but different kinetics for the hydrogenation of 6-methyl-5-hepten-2-one under hydrogen pressure. Characterization of the six supported catalysts suggested that the intrinsic geometry of each of the phosphonate-derivatized 2,2′-bipyridines leads to supported catalysts with different microstructures and different arrangements of the RhL2 species at the surface of the solid, which thereby affect their reactivity.

Csp2-Br bond activation of Br-pyridine by neophylpalladacycle: Formation of binuclear seven-membered palladacycle and bipyridine species

In this work, the synthesis and reactivity of seven-membered palladacycles are described, and a novel bi-pyridine synthesis in a catalytic pathway is reported. Neophyl-palladacycle(i) reacts with an excess of 2-Br-pyridine, giving the desired new binuclear seven-membered palladacycle (1) and unexpectedly, a bipyridine complex, [Pd(BiPy)Br2]. ESI-HRMS experiments show that fragmentation of the Pd-Br bond in 1 can take place producing unusual two coordinated Pd(ii) molecular ions, [Pd(NeoPyR)]+.

Upconverted photosensitization of Tb visible emission by NIR Yb excitation in discrete supramolecular heteropolynuclear complexes

Addition of Tb3+ salts to a solution of a (YbLD) complex in D2O resulted in the formation of [(YbLD)2Tbx] (x = 1 to 3) complexes that, upon NIR excitation at 980 nm, showed an unprecedented Yb to Tb upconversion sensitization phenomenon resulting in the observation of the typical green emission of Tb.