74104-57-7

Basic information

• Product Name: α-(N-Acetylamino-)-4-methylacetophenon
• Synonyms: α-(N-Acetylamino-)-4-methylacetophenon
• CAS NO: 74104-57-7
• Molecular Weight: 191.23
• Mol File: 74104-57-7.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: α-(N-Acetylamino-)-4-methylacetophenon(CAS DataBase Reference)
• NIST Chemistry Reference: α-(N-Acetylamino-)-4-methylacetophenon(74104-57-7)
• EPA Substance Registry System: α-(N-Acetylamino-)-4-methylacetophenon(74104-57-7)

Safety Data

• Hazardous Substances Data: 74104-57-7(Hazardous Substances Data)

Upstream product

• 6595-30-8 2-azido-1-(4-methylphenyl)ethan-1-one 
• 108-24-7 acetic anhydride 
• 5467-70-9 2-amino-4'-methylacetophenone hydrochloride 
• 75-36-5 acetyl chloride 
• 251988-77-9 N-[2-methyl-1-(4-methyl-benzoyl)-propyl]-acetamide 
• 399035-16-6 N-[1-(4-methyl-benzoyl)-butyl]-acetamide 
• 251988-75-7 N-[2,2-dimethyl-1-(4-methyl-benzoyl)-propyl]-acetamide 
• 122-00-9 para-methylacetophenone 
• 1417611-03-0 2-azido-1-(4'-methylphenyl)ethyl acetate 
• 144924-03-8 2-azido-1-(4-methylphenyl)ethanol 
• 619-41-0 4-(bromoacetyl)toluene 
• 69872-37-3 4-(α-aminoacetyl)toluene 
• 251988-79-1 (1S,2R)-N-[2-methyl-1-(4-methylbenzoyl)butyl]acetamide 
• 240131-35-5 2-(N-acetylamino)-3-methyl-1-(p-methylphenyl)-1-butanone 

Downstream Products

• 149286-03-3 Acetic acid (S)-2-acetylamino-1-p-tolyl-ethyl ester 
• 149403-05-4 (S)-1-(4'-methylphenyl)-2-aminoethanol 
• 68395-78-8 2-methyl-5-(4-methylphenyl)-1,3-oxazole 
• 149342-42-7 N-Acetyl-β-hydroxy-4-methyl-phenaethylamin 

Relevant articles and documents

Stereoselective Yang cyclizations of α-amido ketones

The photocyclization of methyl-substituted α-acetamido butyrophenone derivatives is highly stereoselective and leads to 2-aminocyclobutanols with complete control of three new stereogenic centers.

Catalytic transformation of esters of 1,2-azido alcohols into α-amido ketones

The esters of 1,2-azido alcohols were transformed into α-amido ketones without external oxidants through the Ru-catalyzed formation of N-H imines with the liberation of N2 followed by intramolecular migration of the acyl moiety. A wide range of α-amido ketones were obtained, and one-pot transformation into the corresponding oxazoles (or a thiazole) was demonstrated.

α-Carbonyl substituent effect on the lifetimes of triplet 1,4-biradicals from norrish-type-II reactions

Triplet 1,4-biradicals were generated by Norrish-Type-II hydrogen transfer from cx-heteroatom-substituted -branched butyrophenones 1-6 and detected by laser flash absorption measurements. For three oxy-substituted compounds 2-4 (Rα = OH, OCOMe,