74106-00-6

Basic information

• Product Name: 2-Hydroxy-4-methyl-6-morpholinobenzoesaeure-methylester
• Synonyms: 2-Hydroxy-4-methyl-6-morpholinobenzoesaeure-methylester
• CAS NO: 74106-00-6
• Molecular Weight: 251.282
• Mol File: 74106-00-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-Hydroxy-4-methyl-6-morpholinobenzoesaeure-methylester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Hydroxy-4-methyl-6-morpholinobenzoesaeure-methylester(74106-00-6)
• EPA Substance Registry System: 2-Hydroxy-4-methyl-6-morpholinobenzoesaeure-methylester(74106-00-6)

Safety Data

• Hazardous Substances Data: 74106-00-6(Hazardous Substances Data)

Upstream product

• 55370-56-4 3-Morpholinocrotonsaeure-methylester 
• 74106-17-5 4-(2-Methoxycarbonyl-1-methyl-ethylidene)-morpholin-4-ium; chloride 
• 101471-73-2 methyl ester of trans-β-(morpholino)acrylic acid 

Downstream Products

• 76098-20-9 2-Hydroxy-4-methyl-6-morpholinobenzoesaeure-(2',4'-dichloranilid) 
• 76098-25-4 2-(2'-Piperidino)ethoxy-4-methyl-6-morpholino-benzoesaeuremethylester 
• 76098-23-2 2-Hydroxy-4-methyl-6-morpholinobenzoesaeure-(2'-chlor-4'-nitroanilid) 
• 76098-22-1 2-Hydroxy-4-methyl-6-morpholinobenzoesaeure-(2',4',6'-trichloranilid) 
• 76098-21-0 2-Hydroxy-4-methyl-6-morpholinobenzoesaeure-(2',6'-dichloranilid) 
• 76098-19-6 2-Hydroxy-4-methyl-6-morpholinobenzoesaeure-(4'-chloranilid) 
• 75668-82-5 2-Hydroxy-4-methyl-6-morpholinobenzoesaeure-(3'-trifluormethylanilid) 
• 76098-26-5 2-Acetoxy-4-methyl-6-morpholino-benzoesaeuremethylester 
• 76098-24-3 2-(2'-Dimethylamino)ethoxy-4-methyl-6-morpholino-benzoesaeuremethylester 
• 76098-18-5 2-Hydroxy-4-methyl-6-morpholinobenzoesaeure-(4'-fluoranilid) 
• 60541-54-0 3-morpholino-5-methylphenol 
• 75668-89-2 2,2'-Dihydroxy-3,3'-bis(methoxycarbonyl)-6,6'-dimethyl-4,4'-dimorpholino-biphenyl 
• 75144-18-2 4-Methyl-6-morpholino-3,5-dinitro-salicylsaeuremethylester 
• 75144-17-1 4-Methyl-6-morpholino-5-nitro-salicylsaeuremethylester 

Relevant articles and documents

Chemistry of 4-trimethylsilyl-3-dialkylaminocrotonate esters and the cycloaromatization reactions with enamines

Methyl 4-trimethylsilyl-3-dialkylaminocrotonate is synthesized by the silylation of methyl 3-dialkylaminocrotonate.It reacts with carbonyl electrophiles at its γ-position.The unusual regiochemistry of this reaction is studied and rationalized.It reacts with enamines derived from acyclic ketones to give aromatic compounds in a 3C+3C combination and with enamines derived from cycloketones of 5- to 8-membered rings to give aromatic compounds in a 4C+2C combination.A mechanism for this cycloaromatization reaction is proposed.