742078-66-6

Basic information

• Product Name: (±)-hept-6-yn-2-yl benzoate
• Synonyms: (±)-hept-6-yn-2-yl benzoate
• CAS NO: 742078-66-6
• Molecular Weight: 216.28
• Mol File: 742078-66-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (±)-hept-6-yn-2-yl benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: (±)-hept-6-yn-2-yl benzoate(742078-66-6)
• EPA Substance Registry System: (±)-hept-6-yn-2-yl benzoate(742078-66-6)

Safety Data

• Hazardous Substances Data: 742078-66-6(Hazardous Substances Data)

Upstream product

• 176502-41-3 rac-(trimethylsilyl)hept-6-yne-2-ol 
• 101224-43-5 6-(trimethylsilyl)hex-5-ynoic acid: 
• 68381-00-0 6-Trimethylsilanyl-hex-5-ynoyl chloride 
• 21889-89-4 2,3-epoxy-3-methylcyclohexanone 
• 1193-18-6 3-methylcyclohexen-2-one 
• 928-39-2 hept-6-yn-2-one 
• 69177-44-2 6-hydroxy-1-heptyne 
• 98-88-4 benzoyl chloride 

Downstream Products

• 742078-67-7 rac-13-(benzoyloxy)tetradeca-2,5,8-triyne-1-ol 
• 1361250-48-7 (2S/R,8R)-11-(tert-butyldimethylsilyloxy)-8-hydroxyundec-6-yn-2-yl benzoate 
• 1361250-57-8 (2S/R,8R,E)-11-(tert-butyldimethylsilyloxy)-8-hydroxyundec-9-en-6-yn-2-yl benzoate 
• 1361250-56-7 (2S/R,8R)-8-hydroxy-11-(4-methoxybenzyloxy)undec-6-yn-2-yl benzoate 
• 742078-69-9 methyl rac-19-(benzoyloxy)eicosa-5,8,11,14-tetraynoate 
• 742078-68-8 rac-2-(benzoyloxy)-14-bromotetradeca-6,9,12-triyne 
• 79551-85-2 19-Hydroxyarachidonic acid 

Relevant articles and documents

Transition-metal-catalyzed synthesis of aspergillide B: An alkyne addition strategy

A catalytic enantioselective formal total synthesis of aspergillide B is reported. This linchpin synthesis was enabled by the development of new conditions for Zn-ProPhenol catalyzed asymmetric alkyne addition. This reaction was used in conjunction with ruthenium-catalyzed trans-hydrosilylation to affect the rapid construction of a late-stage synthetic intermediate of aspergillide B to complete a formal synthesis of aspergillide B in a highly efficient manner.