7429-08-5

Basic information

• Product Name: 1-benzoyloxy-1-methyl-1-phenylethane
• Synonyms: 1-benzoyloxy-1-methyl-1-phenylethane
• CAS NO: 7429-08-5
• Molecular Weight: 240.302
• Mol File: 7429-08-5.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: 1-benzoyloxy-1-methyl-1-phenylethane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-benzoyloxy-1-methyl-1-phenylethane(7429-08-5)
• EPA Substance Registry System: 1-benzoyloxy-1-methyl-1-phenylethane(7429-08-5)

Safety Data

• Hazardous Substances Data: 7429-08-5(Hazardous Substances Data)

Upstream product

• 98-82-8 Isopropylbenzene 
• 65-85-0 benzoic acid 
• 617-94-7 1-methyl-1-phenylethyl alcohol 
• 98-88-4 benzoyl chloride 
• 80-15-9 Cumene hydroperoxide 
• 140-29-4 phenylacetonitrile 
• 108-88-3 toluene 
• 93-58-3 benzoic acid methyl ester 
• 74-88-4 methyl iodide 
• 612058-36-3 (1-methyl-1-phenylethoxy)di(phenyl)phosphine 
• 614-45-9 tert-Butyl peroxybenzoate 
• 108-90-7 chlorobenzene 
• 67-64-1 acetone 
• 94-36-0 dibenzoyl peroxide 

Relevant articles and documents

Silver/manganese dioxide nanorod catalyzed hydrogen-borrowing reactions and tert-butyl ester synthesis

Silver/manganese dioxide (Ag@MnO2) nanorods are synthesized and characterized by scanning electron microscopy, transmission electron microscopy, energy dispersive X-ray spectroscopy, X-ray powder diffraction, and X-ray photoelectron spectroscopy. It was discovered that Ag@MnO2 nanorods can realize hydrogen-borrowing reactions in high yields and are also effective for the synthesis of tert-butyl esters from aryl cyanides and tert-butyl hydroperoxide in a short period of time. Mechanistic experiments revealed that this catalytic system acts as a Lewis acid in hydrogen-borrowing reactions, while the synthesis of tert-butyl esters occurs through a radical pathway. This is the first report on the excellent catalytic activity of Ag@MnO2 nanorods as a catalyst.

Efficient O-Acylation of Alcohols and Phenol Using Cp2TiCl as a Reaction Promoter

A method has been developed for the conversion of primary, secondary, and tertiary alcohols, and phenol, into the corresponding esters at room temperature. The method uses a titanium(III) species generated from a substoichiometric amount of titanocene dichloride together with manganese(0) as a reductant, as well as methylene diiodide. It involves a transesterification from an ethyl ester, or a reaction with an acyl chloride. A radical mechanism is proposed for these transformations.

The convenient and useful esterification of bulky tertiary alcohols using strontium compounds

Various esters reacted with metallic strontium and alkyl iodides to give dialkylated products, followed by adding acid chlorides or acid anhydrides to afford the corresponding bulky tert-alcohol esters in good yields.