74338-92-4

Basic information

• Product Name: Benzene, [[1-(bromomethyl)ethenyl]sulfinyl]-
• CAS NO: 74338-92-4
• Molecular Formula: C9H9BrOS
• Molecular Weight: 245.14
• Mol File: 74338-92-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzene, [[1-(bromomethyl)ethenyl]sulfinyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [[1-(bromomethyl)ethenyl]sulfinyl]-(74338-92-4)
• EPA Substance Registry System: Benzene, [[1-(bromomethyl)ethenyl]sulfinyl]-(74338-92-4)

Safety Data

• Hazardous Substances Data: 74338-92-4(Hazardous Substances Data)

Upstream product

• 108-98-5 thiophenol 
• 3055-87-6 3-(phenylthio)propionitrile 
• 63067-91-4 3-hydroxy-2-phenylsulphinylprop-1-ene 
• 123533-73-3 2-phenylsulphinyl-3-p-toluenesulphonyloxyprop-1-ene 
• 74338-75-3 2-cyanoethyl(phenyl)sulfoxide 
• 106-96-7 propargyl bromide 

Downstream Products

• 123533-83-5 N-p-tolyl-3-ethoxycarbonyl-5-phenylsulphinyl-3,4,5,6-tetrahydro-2(1H)-pyridone 
• 138689-92-6 phenyl isopropenyl sulfoxide 
• 123533-76-6 N-p-tolyl-N-(2-phenylsulphinylprop-2-enyl)amine 
• 139371-09-8 4-methoxy-2-(2-phenylsulfinyl-2-propenyl)phenyl 2-phenylsulfinyl-2-propyl ether 
• 63067-91-4 3-hydroxy-2-phenylsulphinylprop-1-ene 
• 79496-93-8 2,3-bis(phenylsulphinyl)prop-1-ene 
• 74338-79-7 C₁₄H₁₂O₂S₂ 

Relevant articles and documents

3-PHENOXY-2-PHENYLSULPHINYLPROP-1-ENE AND 3-BROMO-2-PHENYLSULPHINYLPROP-1-ENE, SYNTHONS FOR N-ALKYLATED CYCLIC ENAMIDES.

2-Alkyl(and aryl)amino-2-phenylsulphinylprop-1-enes (derived from benzylamine, cyclohexylamine, and p-toluidine), underwent conjugate addition with diethyl sodiomalonate to give adducts which cyclised to give N-alkylated lactams.Thermolysis of the lactams results in regioselective elimination of benzenesulphenic acid to give N-alkylated cyclic enamides in good yields.The 3-alkyl(and aryl)amino-2-phenylsulphinylprop-1-enes were conveniently prepared by the addition of benzenesulphenic acid to 3-alkyl(and aryl)aminoprop-1-ynes, and by reaction of 3-bromo- and 3-phenoxy-2-phenylsulphinylprop-1-ene with the appropriate amine.