74347-26-5

Basic information

• Product Name: 1-[4-(1-hydroxycyclohexyl)butyl]cyclohexanol
• Synonyms: 1-[4-(1-hydroxycyclohexyl)butyl]cyclohexanol
• CAS NO: 74347-26-5
• Molecular Weight: 254.413
• Mol File: 74347-26-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-[4-(1-hydroxycyclohexyl)butyl]cyclohexanol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-[4-(1-hydroxycyclohexyl)butyl]cyclohexanol(74347-26-5)
• EPA Substance Registry System: 1-[4-(1-hydroxycyclohexyl)butyl]cyclohexanol(74347-26-5)

Safety Data

• Hazardous Substances Data: 74347-26-5(Hazardous Substances Data)

Upstream product

• 108-94-1 cyclohexanone 
• 23708-47-6 1,4-bis(bromomagnesium)butane 
• 2651-46-9 (4-chlorobutoxy)benzene 
• 78-27-3 1-Ethynylcyclohexan-1-ol 
• 5768-10-5 1,4-bis(1-hydroxycyclohexyl)buta-1,3-diyne 
• 60-29-7 diethyl ether 
• 74-86-2 acetylene 

Relevant articles and documents

3-chloropropyl and 4-chlorobutyl phenyl ethers as sources of 1,3-dilithiopropane and 1,4-dilithiobutane: Sequential reaction with carbonyl compounds

The reaction of 3-chloropropyl and 4-chlorobutyl phenyl ethers (1) with lithium powder and a catalytic amount of DTBB (5% molar) in THF at - 78 °C followed by successive treatment with a carbonyl compound [R1R2CO = ButCHO, Me2CO, (CH2)5CO, (-)-menthone] at -78 to 20 °C and, after 1.5 h at this temperature, with a second one [R3R4CO = Bu1CHO, PhCHO, Me2CO, MeCOPrn, (CH2)5CO, (-)-menthone] at -78 °C leads, after hydrolysis with water, to the corresponding 1,5-and 1,6-diols (2). Because of the competition of two different reductive cleavages, 1,4- and 1,5-diols 3 were also obtained as side-reaction products.