74410-51-8

Basic information

• Product Name: methyl 4,6-O-benzylidene-3-O-benzyl-α-D-altropyranoside
• Synonyms: methyl 4,6-O-benzylidene-3-O-benzyl-α-D-altropyranoside
• CAS NO: 74410-51-8
• Molecular Weight: 372.418
• Mol File: 74410-51-8.mol
• Article Data: 46

Chemical Properties

• CAS DataBase Reference: methyl 4,6-O-benzylidene-3-O-benzyl-α-D-altropyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 4,6-O-benzylidene-3-O-benzyl-α-D-altropyranoside(74410-51-8)
• EPA Substance Registry System: methyl 4,6-O-benzylidene-3-O-benzyl-α-D-altropyranoside(74410-51-8)

Safety Data

• Hazardous Substances Data: 74410-51-8(Hazardous Substances Data)

Upstream product

• 3162-96-7 methyl 4,6-O-benzylidene-α-D-glucopyranoside 
• 2397-26-4 N,N-dimethyl(chlorophenylmethylene)ammonium chloride 
• 3162-96-7 methyl 4,6-O-benzylidene-β-D-galactopyranoside 
• 100-39-0 benzyl bromide 
• 3162-96-7 methyl-4,6-O-phenylmethylene-α-D-mannopyranoside 
• 73395-14-9 methyl (R,R)-2,3:4,6-di-O-benzylidene-α-D-mannopyranoside 
• 100-51-6 benzyl alcohol 
• 3150-15-0 methyl 2,3-anhydro-4,6-O-benzilidene-α-D-mannopyranoside 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 2641-79-4 methyl 2,3,4,6-tetrakis-O-trimethylsilyl-α-D-glucopyranoside 
• 100-52-7 benzaldehyde 
• 492-62-6 alpha-D-glucopyranose 
• 97-30-3 methyl-alpha-D-glucopyranoside 
• 611-74-5 N,N-dimethylbenzamide 

Downstream Products

• 90593-22-9 Methyl 3-O-benzyl-4,6-O-benzylidene-2-O-<(trifluoromethyl)sulfonyl>-α-D-glucopyranoside 
• 129031-01-2 methyl 3-O-benzyl-4,6-O-benzylidene-2-O-(2,3,4-tri-O-benzyl-β-L-rhamnopyranosyl)-β-D-galactopyranoside 
• 94061-91-3 (4aR,6R,8S,8aS)-8-Benzyloxy-6-methoxy-2-phenyl-tetrahydro-pyrano[3,2-d][1,3]dioxin-7-one 
• 31022-29-4 methyl 3,6-di-O-benzyl-α-D-galactopyranoside 
• 57783-73-0 methyl 3,4-di-O-benzyl-α-D-mannopyranoside 
• 136632-92-3 methyl 4,6-O-benzylidene-3-O-benzyl-2-O-(methoxycarbonylmethyl)-α-D-mannopyranoside 
• 74410-50-7 methyl 3-O-benzyl-4,6-O-benzylidene-α-D-ribo-hexopyranosid-2-ulose 
• 57783-73-0 methyl 3,4-di-O-benzyl-β-D-mannopyranoside 
• 14218-32-7 Toluene-4-sulfonic acid (4aS,6R,7S,8R,8aS)-8-benzyloxy-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester 
• 129031-02-3 methyl 3-O-benzyl-4,6-O-benzylidene-2-O-(2,3,4-tri-O-acetyl-α-L-rhamnbopyranosyl)-β-D-galactopyranoside 
• 158799-80-5 methyl 3-O-benzyl-4,6-O-benzylidene-2-O-(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl)-α-D-mannopyranoside 
• 65827-58-9 1,2,4,6-tetra-O-acetyl-3-O-benzyl-α-D-mannopyranoside 
• 80680-58-6 methyl 3-O-benzyl-4,6-O-benzylidene-2-O-(N-imidazole-1-sulfonyl)-α-D-glucopyranoside 
• 194039-07-1 methyl 3-O-benzyl-α-D-altropyranoside 

Relevant articles and documents

Deprotection selective, par transfert d'hydrogene, du groupe OH-2 dans le methyl-2,3-di-O-benzyl-4,6-O-benzylidene-α-D-glucopyranoside

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A Chiral Copper Catalyzed Site-Selective O-Alkylation of Carbohydrates

Highly regioselective alkylation of sugar hydroxyl groups has always been an important challenge in carbohydrate chemistry, especially for the selective alkylation of trans diols, there is no direct and efficient catalytic method so far. A chiral copper c

Both d - And l -Glucose Polyphosphates Mimic d - myo-Inositol 1,4,5-Trisphosphate: New Synthetic Agonists and Partial Agonists at the Ins(1,4,5)P3Receptor

Chiral sugar derivatives are potential cyclitol surrogates of the Ca2+-mobilizing intracellular messenger d-myo-inositol 1,4,5-trisphosphate [Ins(1,4,5)P3]. Six novel polyphosphorylated analogues derived from both d- and l-glucose were synthesized. Binding to Ins(1,4,5)P3 receptors [Ins(1,4,5)P3R] and the ability to release Ca2+ from intracellular stores via type 1 Ins(1,4,5)P3Rs were investigated. β-d-Glucopyranosyl 1,3,4-tris-phosphate, with similar phosphate regiochemistry and stereochemistry to Ins(1,4,5)P3, and α-d-glucopyranosyl 1,3,4-tris-phosphate are full agonists, being equipotent and 23-fold less potent than Ins(1,4,5)P3, respectively, in Ca2+-release assays and similar to Ins(1,4,5)P3 and 15-fold weaker in binding assays. They can be viewed as truncated analogues of adenophostin A and refine understanding of structure-activity relationships for this Ins(1,4,5)P3R agonist. l-Glucose-derived ligands, methyl α-l-glucopyranoside 2,3,6-trisphosphate and methyl α-l-glucopyranoside 2,4,6-trisphosphate, are also active, while their corresponding d-enantiomers, methyl α-d-glucopyranoside 2,3,6-trisphosphate and methyl α-d-glucopyranoside 2,4,6-trisphosphate, are inactive. Interestingly, both l-glucose-derived ligands are partial agonists: they are among the least efficacious agonists of Ins(1,4,5)P3R yet identified, providing new leads for antagonist development.