74437-39-1

Basic information

• Product Name: 2-Phenylnorbornadiene
• Synonyms: 2-Phenylnorbornadiene
• CAS NO: 74437-39-1
• Molecular Formula: C₁₃H₁₂
• Molecular Weight: 0
• Mol File: 74437-39-1.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 257.2°C at 760 mmHg
• Flash Point: 104.6°C
• Appearance: /
• Density: 1.092g/cm³
• Vapor Pressure: 0.0237mmHg at 25°C
• Refractive Index: 1.618
• CAS DataBase Reference: 2-Phenylnorbornadiene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Phenylnorbornadiene(74437-39-1)
• EPA Substance Registry System: 2-Phenylnorbornadiene(74437-39-1)

Safety Data

• Hazardous Substances Data: 74437-39-1(Hazardous Substances Data)

Usage

InChI:InChI=1/C13H12/c1-2-4-11(5-3-1)13-9-10-6-7-12(13)8-10/h1-7,9-10,12H,8H2

Upstream product

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Downstream Products

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Relevant articles and documents

Synthetic Equivalents to Substituted Acetylenes in Cycloaddition Reactions. Dienophilic Reactivity of 2-Methyl-, 2-Phenyl- and 2,3-Trimethylene-1,4-Benzodithiins-1,4-Tetroxides

Dienophiles 2-methyl-1,4-benzodithiin-1,4-tetroxide (3a), 2-phenyl-1,4-benzodithiin-1,4-tetroxide (3b) and 2,3-trimethylene-1,4-benzodithiin-1,4-tetroxide (3c) have been prepared with different methods starting from benzene-1,2-dithiol (1).Their reactivit

BIS(TERT-BUTYLSULFONYL)ACETYLENE AS A GENERAL SYNTHETIC EQUIVALENT OF ALKYNES IN DIELS-ALDER CHEMISTRY. II: REDUCTIVE AND ALKYLATIVE DESULFONYLATIONS OF BICYCLIC 1-ALKYL-2-(TERT-BUTYLSULFONYL)ETHENES

Both reductive and alkylative desulfonylations of bicyclic vinyl sulfones derived from Diels-Alder cycloadducts of bis(tert-butylsulfonyl)acetylene (1) are described.These transformations establish the synthetic equivalence of 1 with acetylene, 1-alkynes

1,2-BIS(PHENYLSULFONYL)ALKENES AS VERSATILE GROUPS IN ORGANIC SYNTHESIS: THE PREPARATION OF ALKYL- AND ARYL-SUBSTITUTED NORBORNADIENES VIA THE DIELS-ALDER CYCLOADDITION - GRIGNARD REACTION - DESULFONYLATION SEQUENCE

A synthetic methodology for the preparation of the formal Diels-Alder cycloadducts of alkyl- and aryl-substituted acetylenes which exemplifies the utility of bis(phenylsulfonyl)alkenes 1 in organic synthesis is presented.The procedure entails -cycloaddition of (e)-1,2-bis(phenylsulfonyl)-1-chloroethylene (4), grignard reaction and desulfonylation; each step occurs in high yield.