74516-54-4

Basic information

• Product Name: 2-HYDROXY-5-METHOXY-4-METHYL-BENZALDEHYDE
• Synonyms: 2-HYDROXY-5-METHOXY-4-METHYL-BENZALDEHYDE
• CAS NO: 74516-54-4
• Molecular Formula: C₉H₁₀O₃
• Molecular Weight: 166.17
• Mol File: 74516-54-4.mol
• Article Data: 6

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-HYDROXY-5-METHOXY-4-METHYL-BENZALDEHYDE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-HYDROXY-5-METHOXY-4-METHYL-BENZALDEHYDE(74516-54-4)
• EPA Substance Registry System: 2-HYDROXY-5-METHOXY-4-METHYL-BENZALDEHYDE(74516-54-4)

Safety Data

• Hazardous Substances Data: 74516-54-4(Hazardous Substances Data)

Upstream product

• 4925-88-6 2,5-dimethoxy-4-methylbenzaldehyde 
• 50-00-0 formaldehyd 
• 14786-82-4 4-hydroxy-2-methylanisole 
• 32723-67-4 3-methyl-4-anisaldehyde 
• 24973-22-6 3-methoxy-4-methylbenzaldehyde 

Downstream Products

• 74516-55-5 2-(benzyloxy)-4-methyl-5-methoxybezaldehyde 
• 899822-71-0 3-bromo-2-hydroxy-5-methoxy-4-methylbenzaldehyde 
• 899822-72-1 3-bromo-2,5-dimethoxy-4-methylbenzaldehyde 
• 899822-74-3 3-bromo-1,2,5-trimethoxy-4-methylbenzene 
• 899822-73-2 1-bromo-2,5-dimethoxy-3-hydroxy-6-methylbenzene 
• 899822-84-5 formic acid 3-bromo-2,5-dimethoxy-4-methylphenyl ester 
• 899822-82-3 5-methoxy-2-methyl-3-(toluene-4-sulfinyl)-[1,4]benzoquinone 
• 899822-85-6 1,2,5-trimethoxy-4-methyl-3-(toluene-4-sulfanyl)benzene 
• 899822-68-5 (S_S)-5-methoxy-2-methyl-3-(toluene-4-sulfinyl)-[1,4]benzoquinone 
• 899822-81-2 (+/-)-1,2,5-trimethoxy-4-methyl-3-(toluene-4-sulfinyl)benzene 
• 899822-75-4 (S_S)-1,2,5-trimethoxy-4-methyl-3-(toluene-4-sulfinyl)benzene 
• 115392-14-8 (+/-)-1-<2-(benzyloxy)-4-methyl-5-methoxyphenyl>-2-aminopropane 
• 74516-56-6 1-<(2-benzyloxy)-4-methyl-5-methoxyphenyl>-2-nitropropene 
• 123164-32-9 4-methoxycurcuphenol 

Relevant articles and documents

Pd-Catalyzed Ortho C-H Hydroxylation of Benzaldehydes Using a Transient Directing Group

The direct Pd-catalyzed ortho C-H hydroxylation of benzaldehydes was achieved using 4-chloroanthranilic acid as the transient directing group, 1-fluoro-2,4,6-trimethylpyridnium triflate as the bystanding oxidant, and p-toluenesulfonic acid as the putative oxygen nucleophile. The unusual C-H chlorination and polyfluoroalkoxylation reactions signaled the importance of external nucleophiles to the outcome of Pd(IV) reductive eliminations.

BENZOFURAN AND BENZOTHIOPHENE-2-CARBOXYLIC ACID AMIDE DERIVATIVES

The present invention relates to compounds of formula I wherein X, A and R1 to R4 are as defined in the description and claims, and pharmaceutically acceptable salts thereof. The compounds are useful for the treatment and/or prevention of diseases which are associated with the modulation of H3 receptors.

Asymmetric Diels-Alder reactions of a new enantiomerically pure sulfinylquinone: A straightforward access to functionalized Wieland-Miescher ketone analogues with (R) absolute configuration

An efficient and highly stereocontrolled preparation, on a large scale, of two new Wieland-Miescher-type diketones is described. The approach centers on a diastereoselective Diels-Alder reaction using a new enantiomerically pure sulfinylquinone. Mechanist