74558-90-0

Basic information

• Product Name: bis(triphenylphosphane)iminium(pentafluorophenyl)chlorogold(I)
• Synonyms: bis(triphenylphosphane)iminium(pentafluorophenyl)chlorogold(I)
• CAS NO: 74558-90-0
• Molecular Weight: 938.066
• Mol File: 74558-90-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: bis(triphenylphosphane)iminium(pentafluorophenyl)chlorogold(I)(CAS DataBase Reference)
• NIST Chemistry Reference: bis(triphenylphosphane)iminium(pentafluorophenyl)chlorogold(I)(74558-90-0)
• EPA Substance Registry System: bis(triphenylphosphane)iminium(pentafluorophenyl)chlorogold(I)(74558-90-0)

Safety Data

• Hazardous Substances Data: 74558-90-0(Hazardous Substances Data)

Upstream product

• 21050-13-5 bis(triphenylphosphine)iminium chloride 

Downstream Products

• 7440-57-5 gold 
• 277303-32-9 Au(C₆F₅)C₂H^(1-)*((C₆H₅)3P)2N⁽¹⁺⁾=Au(C₆F₅)C₂H(((C₆H₅)3P)2N) 
• 1001197-25-6 PPN[Au(p-CH₃-C₆H₄-CC-S)(C₆F₅)] 
• 497065-02-8 AuC₆F₅(P(C₆H₅)2CC)Au(C₆F₅)^(1-)*N(P(C₆H₅)3)2⁽¹⁺⁾=Au₂(C₆F₅)2P(C₆H₅)2CC(N(P(C₆H₅)3)2) 

Relevant articles and documents

Complexes with S-donor ligands. 5. ? Syntheses of the first (hydrosulfido)- and anionic sulfidoorganogold(I) complexes. Crystal and molecular structure of (Et4N)2[{Au(C6F5)} 3(μ3-S)]·0.5MeC(O)Et

Complexes Q[Au(R)Cl] react with H2S in the presence of diethylamine to give the corresponding organo(hydrosulfido)gold(I) complexes Q[Au(R)(SH)] [R = C6F5, Q = Ph3P=N=PPh3 = PNP, Bu4N; Q = PNP, R = C6H4NO2-2, C6H2(NO2)3-2,4,6]. Under the same reaction conditions, Me4N[Au(C6F5)Cl] gives the bridging organo(μ3-sulfido)gold(I) complex (Me4N)2[{Au(C6F5)} 3(μ3-S)], whereas Et4N[Au(C6F5)Cl] gives Et4N[Au(C6F5)SH] or (Et4N)2[{Au(C6F5)} 3(μ3-S)] depending on the workup procedure. The crystal structure of Et4N-[{Au(C6F5)}3(μ 3-S)]·0.5MeC(O)Et has been determined. The Au?Au contacts are 3.1844, 3.2773, and 3.4772 A?, with corresponding angles 86.68, 90.31, and 97.65° at sulfur.