74563-17-0

Basic information

• Product Name: C₂₀H₁₄O^(2-)*2Na⁽¹⁺⁾
• Synonyms: C₂₀H₁₄O^(2-)*2Na⁽¹⁺⁾
• CAS NO: 74563-17-0
• Molecular Weight: 316.31
• Mol File: 74563-17-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₀H₁₄O^(2-)*2Na⁽¹⁺⁾(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₀H₁₄O^(2-)*2Na⁽¹⁺⁾(74563-17-0)
• EPA Substance Registry System: C₂₀H₁₄O^(2-)*2Na⁽¹⁺⁾(74563-17-0)

Safety Data

• Hazardous Substances Data: 74563-17-0(Hazardous Substances Data)

Upstream product

• 5471-63-6 1,3-diphenylisobenzofuran 

Downstream Products

• 74563-24-9 Dimethyl trans-1,3-diphenylphthalan-1,3-dicarboxylate 
• 74563-23-8 Dimethyl cis-1,3-diphenylphthalan-1,3-dicarboxylate 
• 21596-49-6 1,3-dihydro-1,3-diphenyl-isobenzofuran 
• 74563-32-9 1,3-diphenyl-4,5,6,7-tetrahydroisobenzofuran 
• 796-30-5 1,4-diphenylnaphthalene 
• 74563-31-8 o-(α-Phenylneopentyl)benzophenone 
• 1159-86-0 o-dibenzoylbenzene 
• 5471-63-6 1,3-diphenylisobenzofuran 
• 74563-21-6 1,3-Dimethyl-1,3-diphenylphthalan 
• 74563-20-5 1,3-Dimethyl-1,3-diphenylphthalan 
• 74563-27-2 1,3-Diphenyl-1,3-butanophthalan 
• 74563-25-0 1,3-Diphenyl-1,3-ethanophthalan 
• 74563-26-1 1,3-Diphenyl-1,3-propanophthalan 
• 7111-67-3 1,3-dihydro-1,3-diphenyl-isobenzofuran 

Relevant articles and documents

Reductive Metalation of 1,3-Diphenylisobenzofuran. Stereoselective Formation of Cis Products

1,3-Diphenylisobenzofuran was reduced in tetrahydrofuran by alkali metals to a dianion.This dianion on protonation, methylation, or carboxylation gave products which were predominantly cis.It is suggested that the dianion or the intermediate monoreacted monoanion adopts a preferred conformation in which steric interaction between the phenyl substituents is minimized and orbital overlap between the carbanion and the benzene ring is maximized.By use of this stereoselectivity of the dianion, a series of 1,3-polymethylene-bridged 1,3-diphenylphthalans was prepared.The possibility of single electron transfer during the alkylation of the dianion was examined by alkylating the dianion with tert-butyl halides.Complex reaction mixtures were formed but extensive alkylation occurred and mono- and dialkylation products were characterized.