74697-53-3

Basic information

• Product Name: Methanone, bis[2-(phenylmethoxy)phenyl]-
• CAS NO: 74697-53-3
• Molecular Formula: C27H22O3
• Molecular Weight: 394.47
• Mol File: 74697-53-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Methanone, bis[2-(phenylmethoxy)phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Methanone, bis[2-(phenylmethoxy)phenyl]-(74697-53-3)
• EPA Substance Registry System: Methanone, bis[2-(phenylmethoxy)phenyl]-(74697-53-3)

Safety Data

• Hazardous Substances Data: 74697-53-3(Hazardous Substances Data)

Upstream product

• 835-11-0 2,2'-dihydroxybenzophenone 
• 100-39-0 benzyl bromide 
• 5896-17-3 2-(phenylmethoxy)benzaldehyde 
• 31575-75-4 2-bromophenyl benzyl ether 

Relevant articles and documents

Manganese-promoted cleavage of acetylacetonate resembling the β-diketone cleaving dioxygenase (Dke1) reactivity

We here report a manganese-based oxidative cleavage of inactivated acetylacetonate, the mechanistic pathway of which resembles Dke1-catalyzed reactions of β-diketone and α-keto acid. This oxidative transformation proceeds through an acetylacetonate-pyruvate-oxalate pathway, which can be terminated at the stage of pyruvate through ligand/solvent variation. XRD, time-dependent GC-MS, and isotope-labeling studies suggested that our system represents the same cleaving specificity and dioxygenase-like reactivity of Dke1.