7470-23-7

Basic information

• Product Name: methyl (2Z)-3-phenanthren-9-ylprop-2-enoate
• CAS NO: 7470-23-7
• Molecular Formula: C₁₈H₁₄O₂
• Molecular Weight: 262.3026
• Mol File: 7470-23-7.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 454.3°C at 760 mmHg
• Flash Point: 307.9°C
• Density: 1.199g/cm³
• Vapor Pressure: 1.93E-08mmHg at 25°C
• Refractive Index: 1.697
• CAS DataBase Reference: methyl (2Z)-3-phenanthren-9-ylprop-2-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (2Z)-3-phenanthren-9-ylprop-2-enoate(7470-23-7)
• EPA Substance Registry System: methyl (2Z)-3-phenanthren-9-ylprop-2-enoate(7470-23-7)

Safety Data

• Hazardous Substances Data: 7470-23-7(Hazardous Substances Data)

Upstream product

• 186581-53-3 diazomethane 
• 54522-77-9 trans-β-(9-phenanthryl)acrylic acid 
• 573-17-1 9-bromophenanthrene 
• 292638-85-8 acrylic acid methyl ester 
• 4707-71-5 Phenanthrene-9-carboxaldehyde 

Relevant articles and documents

Synthesis and Immobilization of Metal Nanoparticles Using Photoactive Polymer-Decorated Zeolite L Crystals and Their Application in Catalysis

A facile route to generate Au and Pd nanoparticles (NPs) on zeolite L crystals decorated with photoactive polymer brushes is described. The polymers used in this approach serve a dual role: Upon irradiation with UV light, they release highly reducing ketyl radicals in a Norrish-Type-I reaction. These radicals serve as one electron donors to reduce metal salts to the corresponding metal NPs. At the same time the polymer shell stabilizes the in situ generated metal NPs. It is shown that the zeolite-polymer-NP composites can be used as recyclable catalysts for the oxidation of benzylic alcohols to aldehydes and the stereoselective semihydrogenation of alkynes to Z-alkenes. The polymer shell in these hybrid catalysts protects the NPs from aggregation and also alters their catalytic properties. (Figure presented.).

Accelerated Heck reaction using ortho-palladated complex in a nonaqueous ionic liquid with controlled microwave heating

The activity of {Pd[C6H2(CH2CH 2NH2)-(OMe)2,3,4] (μ-Br)}2 complex was investigated in the Heck-Mizoroki C-C cross-coupling reaction under conventional heating and microwave irradiation conditions in molten salt tetrabutylammonium bromide as the solvent and promoter at 130 °C. This complex in these conditions is an active and efficient catalyst for the Heck reaction of aryl iodides, bromides and even chlorides, and also arenesulfonyl chlorides. Copyright

Heck coupling reaction using monomeric ortho-palladated complex of 4-methoxy- benzoylmethylenetriphenylphosphorane under microwave irradiation

The activity of [Pd(C6H4CH2 NH 2-κ2-C-N)PPh3MOBPPY]OTf complex, A (MOBPPY = 4-methoxybenzoylmethylenetriphenyl- phosphoraneylide), was investigated in the Heck-Mizoroki C-C cross-coupling reaction under conventional heating and microwave irradiation conditions. The complex is an active and efficient catalyst for the Heck reaction of aryl halides. The yields were excellent using a catalytic amount of [Pd(C6H4CH 2 NH2-κ2-C-N)PPh3MOBPPY]OTf complex in N-methyl-2-pyrrolidinone (NMP) at 130 °C and 600 W. In comparison to conventional heating conditions, the reactions under microwave irradiation gave higher yields in shorter reaction times. Copyright