7472-83-5

Basic information

• Product Name: DIETHYL (3-OXO-1,3-DIPHENYLPROPYL)MALONATE
• Synonyms: DIETHYL (3-OXO-1,3-DIPHENYLPROPYL)MALONATE
• CAS NO: 7472-83-5
• Molecular Formula: C₂₂H₂₄O₅
• Molecular Weight: 368.423
• Mol File: 7472-83-5.mol
• Article Data: 50

Chemical Properties

• Boiling Point: 495.6°Cat760mmHg
• Flash Point: 214.8°C
• Appearance: /
• Density: 1.144g/cm³
• Vapor Pressure: 5.81E-10mmHg at 25°C
• Refractive Index: 1.542
• CAS DataBase Reference: DIETHYL (3-OXO-1,3-DIPHENYLPROPYL)MALONATE(CAS DataBase Reference)
• NIST Chemistry Reference: DIETHYL (3-OXO-1,3-DIPHENYLPROPYL)MALONATE(7472-83-5)
• EPA Substance Registry System: DIETHYL (3-OXO-1,3-DIPHENYLPROPYL)MALONATE(7472-83-5)

Safety Data

• Hazardous Substances Data: 7472-83-5(Hazardous Substances Data)

Usage

InChI:InChI=1/C22H24O5/c1-3-26-21(24)20(22(25)27-4-2)18(16-11-7-5-8-12-16)15-19(23)17-13-9-6-10-14-17/h5-14,18,20H,3-4,15H2,1-2H3

Upstream product

• 64-17-5 ethanol 
• 4475-13-2 (3-oxo-1,3-diphenyl-propyl)-malonic acid 
• 94-41-7 benzalacetophenone 
• 105-53-3 diethyl malonate 
• 996-82-7 sodium diethylmalonate 
• 60-29-7 diethyl ether 
• 614-47-1 1,3-diphenyl-propen-3-one 
• 742-43-8 1,3-diphenyl-3-(N-phenylamino)propanone 
• 685-87-0 Diethyl 2-bromomalonate 
• 5292-53-5 diethyl benzalmalonate 
• 3433-56-5 1-(1-phenylvinyl)pyrrolidine 
• 51246-20-9 1-phenyl-1-iodoethylene 
• 98-81-7 1-bromovinylbenzene 
• 28143-79-5 1-phenyl vinyl triflate 

Downstream Products

• 77670-31-6 ethyl γ-benzoyl-α-ethoxycarbonyl-α-methyl-β-phenylbutyrate 
• 609-08-5 Diethyl methylmalonate 
• 614-47-1 1,3-diphenyl-propen-3-one 
• 5456-53-1 5-oxo-3,5-diphenylpentanoic acid 
• 72028-23-0 C₁₈H₂₂N₆O₂ 
• 4475-13-2 (3-oxo-1,3-diphenyl-propyl)-malonic acid 
• 105-53-3 diethyl malonate 
• 77565-69-6 methyl 5-oxo-3,5-diphenylpentanoate 
• 1186241-84-8 diethyl 2-(2,3-dioxo-1,3-diphenylpropyl)malonate 
• 6327-84-0 diethyl trans-2-benzoyl-3-phenylcyclopropane-1,1-dicarboxylate 
• 1172113-15-3 diethyl 2-iodo-2-(3-oxo-1,3-diphenylpropyl)malonate 
• 69867-75-0 2,4-diphenylcyclopent-2-enone 

Relevant articles and documents

Ba(OH)2 as Catalyst in Organic Reactions IV. Reaction Between Coumarin and Diethyl Malonate

The reaction of diethyl malonate and coumarin catalyzed by an activated barium hydroxide catalyst (C-200) in a solid-liquid-system is described.No Michael addition takes place.An unusual nucleophilic addition-elimination process to the C = O bond of couma

Exploring bis-(amino)cyclopropenylidene as a non-covalent Br?nsted base catalyst in conjugate addition reactions

Bis-(amino)cyclopropenylidene has been utilised as a non-covalent Br?nsted base catalyst in the 1,6-conjugate addition of carbon nucleophiles to p-QMs. This protocol makes it possible to access unsymmetrical diaryl- and triarylmethanes in good to excellen

On-water magnetic NiFe2O4 nanoparticle-catalyzed Michael additions of active methylene compounds, aromatic/aliphatic amines, alcohols and thiols to conjugated alkenes

Here, we have demonstrated the Michael addition of active methylene compounds, aromatic/aliphatic amines, thiols and alcohols to conjugated alkenes using magnetic nano-NiFe2O4 as reusable catalyst in water. Nano-NiFe2O4 efficiently catalyzed the formation of C-C and C-X (X = N, S, O etc.) bond through 1,4-addition reactions.

Highly enantioselective Michael addition of diethyl malonate to chalcones catalyzed by cinchona alkaloids-derivatived bifunctional tertiary amine-thioureas bearing multiple hydrogen-bonding donors

Chalcones are still challenge substrates in Michael reactions, and only limited success has been achieved. This work describes a highly enantioselective Michael addition of diethyl malonate with chalcones catalyzed by cinchona alkaloids-derivatived bifunctional tertiary amine-thioureas bearing multiple hydrogen-bonding donors.