74793-47-8Relevant articles and documents
Platinum(IV)-Catalyzed Synthesis of Unsymmetrical Polysubstituted Benzenes via Intramolecular Cycloaromatization Reaction
Zheng, Shuyan,Zhang, Jinghua,Shen, Zhengwu
supporting information, p. 2803 - 2808 (2015/09/28)
A one-pot synthesis of polysubstituted benzene derivatives was achieved via a platinum(IV)-catalyzed intramolecular cycloaromatization reaction. The reaction proceeds via a tandem skeletal rearrangment, dehydration and double bond isomerization, which proved to be very useful for the syntheses of a range of interesting polyalkyl-substituted benzenes.
Intramolecular additions of alcohols and carboxylic acids to inert olefins catalyzed by silver(I) triflate
Yang, Cai-Guang,Reich, Nicholas W.,Shi, Zhangjie,He, Chuan
, p. 4553 - 4556 (2007/10/03)
(Chemical Equation Presented) Intramolecular additions of hydroxyl or carboxyl groups to inert olefins catalyzed by simple silver(I) triflate are described. Good to excellent yields can be obtained for a range of substrates under relatively mild conditions. This reaction represents one of the simplest methods to construct cyclic ethers or lactones.