74827-82-0

Basic information

• Product Name: Carbonic acid, (4-nitrophenyl)methyl 1,4,6,6a,7,10,10a,11-octahydro-12-hydroxy-1-methoxy-6,11-dioxo-8,10 -bis[(trimethylsilyl)oxy]-1,4-ethanonaphthacen-5-yl ester
• CAS NO: 74827-82-0
• Molecular Formula: C35H41NO11Si2
• Molecular Weight: 707.882
• Mol File: 74827-82-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Carbonic acid, (4-nitrophenyl)methyl 1,4,6,6a,7,10,10a,11-octahydro-12-hydroxy-1-methoxy-6,11-dioxo-8,10 -bis[(trimethylsilyl)oxy]-1,4-ethanonaphthacen-5-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbonic acid, (4-nitrophenyl)methyl 1,4,6,6a,7,10,10a,11-octahydro-12-hydroxy-1-methoxy-6,11-dioxo-8,10 -bis[(trimethylsilyl)oxy]-1,4-ethanonaphthacen-5-yl ester(74827-82-0)
• EPA Substance Registry System: Carbonic acid, (4-nitrophenyl)methyl 1,4,6,6a,7,10,10a,11-octahydro-12-hydroxy-1-methoxy-6,11-dioxo-8,10 -bis[(trimethylsilyl)oxy]-1,4-ethanonaphthacen-5-yl ester(74827-82-0)

Safety Data

• Hazardous Substances Data: 74827-82-0(Hazardous Substances Data)

Upstream product

• 475-38-7 5,8-Dihydroxy-1,4-naphthoquinone 
• 74827-78-4 p-nitrocarbobenzoxy naphthazarin 
• 2161-90-2 1-methoxy-1,3-cyclohexadiene 
• 61838-70-8 (E)-1,3-bis(trimethylsilyloxy)buta-1,3-diene 
• 74827-80-8 (4-nitrophenyl)methyl 1,4,9,10-tetrahydro-8-hydroxy-1-methoxy-9,10-dioxo-1,4-ethanoanthracen-5-yl carbonate 
• 74827-79-5 1,4,4a,9,9a,10-hexahydro-8-hydroxy-1-methoxy-9,10-dioxo-1,4-ethanoanthracen-5-yl(4-nitrophenyl)methyl carbonate 

Downstream Products

• 21794-55-8 (+/-)-7-epi-daunomycinone 
• 88876-12-4 1,4,6a,9,10,10a-hexahydro-10,12-dihydroxy-1-methoxy-6,8,11(7H)-trioxo-1,4-ethanonaphthacen-5-yl(4-nitrophenyl)methyl carbonate 

Relevant articles and documents

AN EFFICIENT, REGIOSPECIFIC SYNTHESIS OF (+/-)-DAUNOMYCINONE

The development of a general strategy for the control of regiochemistry in the Diels-Alder reactions of substituted naphthazarins is described.Application of this strategy to the synthesis of (+/-)-daunomycinone (2) employs two successive regiochemically controlled Diels-Alder reactions and leads to a ten-step, regiospecific synthesis of (+/-)-2 in 36percent overall yield (Scheme 4).