74829-78-0Relevant articles and documents
Ir-Catalyzed Remote Functionalization by the Combination of Deconjugative Chain-Walking and C-H Activation Using a Transient Directing Group
Tang, King Hung Nigel,Uchida, Kanako,Nishihara, Kazuki,Ito, Mamoru,Shibata, Takanori
, p. 1313 - 1317 (2022/02/23)
An Ir-catalyzed reaction of N-benzylideneanilines with functionalized alkenes such as α,β-unsaturated esters gave ortho-substituted benzaldehyde derivatives with a functional group at the remote position after acidic treatment. The present transformation
Facile method for solid-phase synthesis of vinyl sulfones using polystyrene-supported selenomethyl aryl sulfone
Sheng, Shou-Ri,Zhou, Wei,Zhong, Ming-Hua,Liu, Xiao-Ling,Chen, Hui-Zong
, p. 815 - 821 (2007/10/03)
Treatment of novel polystyrene-supported selenomethyl aryl sulfone with LDA followed by alkylation and oxidation elimination efficiently afforded vinyl sulfones in good yields and purities.
Abnormal Four-Membered Ring Formation in Intramolecular Radicalic Cyclization. High Stability of the Alkyl Radical Substituted with Methylthio and p-Tolylsulfonyl Groups
Ogura, Katsuyuki,Sumitani, Naoko,Kayano, Akio,Iguchi, Hirotaka,Fujita, Makoto
, p. 1487 - 1488 (2007/10/02)
Treatment of 5-iodo-1-(methylthio)-1-(p-tolylsulfonyl)-1-pentene with (n-Bu)3SnH and AIBN gave cyclobutane.This is due to the stability of an intermediary radical attached to methylthio and p-tolylsulfonyl groups.