74866-37-8

Basic information

• Product Name: [(2-phenyl-2-propenyl)sulfonyl]benzene
• Synonyms: [(2-phenyl-2-propenyl)sulfonyl]benzene
• CAS NO: 74866-37-8
• Molecular Formula: C₁₅H₁₄O₂S
• Molecular Weight: 258.33546
• Mol File: 74866-37-8.mol
• Article Data: 32

Chemical Properties

• Melting Point: 43-45 °C(Solv: ethanol (64-17-5))
• Boiling Point: 450.8±38.0 °C(Predicted)
• Appearance: /
• Density: 1.166±0.06 g/cm3(Predicted)
• CAS DataBase Reference: [(2-phenyl-2-propenyl)sulfonyl]benzene(CAS DataBase Reference)
• NIST Chemistry Reference: [(2-phenyl-2-propenyl)sulfonyl]benzene(74866-37-8)
• EPA Substance Registry System: [(2-phenyl-2-propenyl)sulfonyl]benzene(74866-37-8)

Safety Data

• Hazardous Substances Data: 74866-37-8(Hazardous Substances Data)

Upstream product

• 3360-54-1 3-bromo-2-phenylprop-1-ene 
• 873-55-2 sodium benzenesulfonate 
• 109045-76-3 (2-phenylprop-1-en-3-yl)trimethylammonium iodide 
• 98-83-9 isopropenylbenzene 
• 108-86-1 bromobenzene 
• 463-49-0 1,2-propanediene 
• 2525-42-0 phenylsulfonylpropa-1,2-diene 
• 98-80-6 phenylboronic acid 
• 98-09-9 benzenesulfonyl chloride 
• 3360-52-9 3-chloro-2-phenylprop-1-ene 
• 16917-32-1 (E)-2-chloro-1-methyl-1-phenylethene 
• 15561-33-8 1-chloro-2-phenylpropan-2-ol 
• 7757-83-7 sodium sulfite 
• 127159-68-6 1-chloro-2-(3,-chloro-2,-pyridyl)-1-propene 

Downstream Products

• 74866-53-8 3-(phenylsulfonyl)-2-phenyl-1-heptene 
• 4469-66-3 4-Phenyl-2-methoxycarbonyl-4-enoic acid methyl ester 
• 74866-55-0 2-phenyl-3-(phenylsulfonyl)-1-hepten-6-one 
• 74866-42-5 2-((Z)-2-Phenyl-hept-2-enyl)-malonic acid dimethyl ester 
• 74866-43-6 2-((Z)-2-Phenyl-hept-2-enyl)-malonic acid dimethyl ester 
• 74866-47-0 2-((Z)-6-Oxo-2-phenyl-hept-2-enyl)-malonic acid dimethyl ester 
• 74866-47-0 2-((Z)-6-Oxo-2-phenyl-hept-2-enyl)-malonic acid dimethyl ester 
• 74866-44-7 (Z)-2-Benzenesulfonyl-4-phenyl-non-4-enoic acid methyl ester 
• 74866-45-8 (Z)-2-Benzenesulfonyl-4-phenyl-non-4-enoic acid methyl ester 
• 127159-32-4 1-bromo-2-phenyl-3-phenylsulphonyl-2-propanol 
• 99522-43-7 (E)-2-(3-phenylprop-2-enyloxy)ethan-1-ol 

Relevant articles and documents

Ni-Catalyzed Reductive Allylation of α-Chloroboronates to Access Homoallylic Boronates

The transition-metal-catalyzed allylation reaction is an efficient strategy for the construction of new carbon-carbon bonds alongside allyl or homoallylic functionalization. Herein we describe a Ni-catalyzed reductive allylation of α-chloroboronates to efficiently render the corresponding homoallylic boronates, which could be readily converted into valuable homoallylic alcohols or amines or 1,4-diboronates. This reaction features a broad substrate scope with good functional group compatibility that is complementary to the existing methods for the preparation of homoallylic boronates.

Copper-Catalyzed Intermolecular Alkynylation and Allylation of Unactivated C(sp3)-H Bonds via Hydrogen Atom Transfer

We describe Cu-catalyzed intermolecular alkynylation and allylation of unactivated C(sp3)-H bonds with singly occupied molecular orbital-philes (SOMO-philes) via hydrogen atom transfer (HAT). Employing N-fluoro-sulfonamide as a HAT reagent, a set of subst

Silver-catalyzed decarboxylative radical allylation of α,α-difluoroarylacetic acids for the construction of CF2-allyl bonds

An efficient silver-catalyzed method of decarboxylative radical allylation of α,α-difluoroarylacetic acids to build CF2-allyl bonds has been developed. Using allylsulfone as an allyl donor, α,α-difluorine substituted arylacetic acids bearing various functional groups are successfully allylated to access a series of 3-(α,α-difluorobenzyl)-1-propylene compounds in moderate to excellent yields in aqueous CH3CN solution under the mild conditions. Experimental studies disclosed that the α-fluorine substitution of arylacetic acid has a great influence on free radical activity and reactivity.