74965-55-2

Basic information

• Product Name: (R)-2-Allyl-6-oxo-cyclohexanecarboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester
• Synonyms: (R)-2-Allyl-6-oxo-cyclohexanecarboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester
• CAS NO: 74965-55-2
• Molecular Weight: 320.472
• Mol File: 74965-55-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-2-Allyl-6-oxo-cyclohexanecarboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-2-Allyl-6-oxo-cyclohexanecarboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester(74965-55-2)
• EPA Substance Registry System: (R)-2-Allyl-6-oxo-cyclohexanecarboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester(74965-55-2)

Safety Data

• Hazardous Substances Data: 74965-55-2(Hazardous Substances Data)

Upstream product

• 2216-51-5 (-)-menthol 
• 74965-53-0 3-Oxo-oct-7-enoic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester 
• 59557-05-0 (L)-menthyl 3-oxobutyrate 
• 1112-56-7 tetravinyltin (IV) 
• 74965-54-1 (R)-2-Oxo-bicyclo[4.1.0]heptane-1-carboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester 

Downstream Products

• 74965-56-3 3-allylcyclohexanone 

Relevant articles and documents

Preparation of Cyclohexanones and Cyclopentanones of High Optical Purity

Cyclization of 3, prepared from 1-menthol, led to a 1:1 mixture of 4 and 5.These diastereomeric ketones, readily separated by chromatography, are versatile intermediates for the preparation of alkylated cyclohexanones.The absolute configuration of 5 was assigned by conversion to the known hydroxy ketal 9.This approach works equally well for the cyclopentane series.Thus, alkylated cyclohexanones and cyclopentanones of known absolute configuration will for the first time be routinely available.