75025-14-8

Basic information

• Product Name: methyl 5-phenyl-3-cyclohexenecarboxylate
• Synonyms: methyl 5-phenyl-3-cyclohexenecarboxylate
• CAS NO: 75025-14-8
• Molecular Weight: 216.28
• Mol File: 75025-14-8.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: methyl 5-phenyl-3-cyclohexenecarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 5-phenyl-3-cyclohexenecarboxylate(75025-14-8)
• EPA Substance Registry System: methyl 5-phenyl-3-cyclohexenecarboxylate(75025-14-8)

Safety Data

• Hazardous Substances Data: 75025-14-8(Hazardous Substances Data)

Upstream product

• 68823-43-8 methyl cis-5-diethylaminocyclohex-3-enecarboxylate 
• 98-80-6 phenylboronic acid 
• 6638-68-2 4,5-dimethyl-2-phenyl-1,3,2-dioxaborolane 
• 144681-41-4 methyl cis-<5-(ethoxycarbonyl)oxy-3-cyclohexene-1-carboxylate> 
• 60729-55-7 cis-methyl 5-acetoxycyclohex-3-enecarboxylate 
• 54911-89-6 cis-methyl 5-hydroxycyclohex-3-enecarboxylate 
• 186581-53-3 diazomethane 
• 16939-57-4 (E)-buta-1,3-dienylbenzene 
• 2495-35-4 benzylacrylate 
• 143-66-8 sodium tetraphenyl borate 
• 960-16-7 tributylphenylstannane 
• 87830-10-2 trans-5-(methoxycarbonyl)-2-cyclohexenyl chloride 
• 115181-98-1 cis-3-Acetoxy-5-carbomethoxycyclohexene 
• 934-56-5 trimethyl(phenyl)stannane 

Relevant articles and documents

A highly active and reusable self-assembled poly(imidazole/palladium) catalyst: Allylic arylation/alkenylation

Gobs of globules: A polymeric imidazole/acrylamide palladium catalyst, MPPI-Pd (M=PdIICl and Pd0), was utilized for the allylic arylation/alkenylation of allylic esters with aryl/alkenylboronic acids and tetraaryl borates. Low catalyst loadings efficiently promoted the reaction with a catalytic turnover number of 20000-1250000. The catalyst can be reused without loss of catalytic activity.

A highly effective (Triphenyl phosphite)palladium catalyst for a cross-coupling reaction of allylic alcohols with organoboronic acids

The cross coupling reaction of aryl and vinyl boronic acids and allylic alcohols proceeded smoothly in toluene or dioxane in the presence of a (triphenyl phosphite)palladium catalyst to give the corresponding allylbenzene derivatives and 1,4-dienes. Neither cocatalysts for promoting C-O bond cleavage of allylic alcohols nor bases for activation of organoboron reagents are required for promoting the coupling process. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.

Cross-Coupling of Aryl Halides and Allyl Acetates with Arylboron Reagents in Water Using an Amphiphilic Resin-Supported Palladium Catalyst

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