75029-37-7

Basic information

• Product Name: 5-Benzoyl-1,3-dimethyluracilbenzoylhydrazon
• Synonyms: 5-Benzoyl-1,3-dimethyluracilbenzoylhydrazon
• CAS NO: 75029-37-7
• Molecular Weight: 362.388
• Mol File: 75029-37-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 5-Benzoyl-1,3-dimethyluracilbenzoylhydrazon(CAS DataBase Reference)
• NIST Chemistry Reference: 5-Benzoyl-1,3-dimethyluracilbenzoylhydrazon(75029-37-7)
• EPA Substance Registry System: 5-Benzoyl-1,3-dimethyluracilbenzoylhydrazon(75029-37-7)

Safety Data

• Hazardous Substances Data: 75029-37-7(Hazardous Substances Data)

Upstream product

• 874-14-6 1,3-dimethyluracil 
• 725-12-2 2,5-bis-(phenyl)-1,3,4-oxadiazole 

Downstream Products

• 75029-44-6 1,3-dimethyl-5-benzoylpyrimidine-2,4(1H,3H)-dione 

Relevant articles and documents

Photochemistry of Heterocycles, 8. The Photoreaction of 2,5-Diaryl-1,3,4-oxadiazoles with 1,3-Dimethyluracils. A New and Simple Synthesis of 1,2,4,5-Tetrazines

Upon UV-irradiation 2,5-diaryl-1,3,4-oxadiazoles 2a-g do not undergo (2+2)-cycloaddition with 1,3-dimethyluracil, but instead ring cleavage occurs to afford the benzoylhydrazones 3a-e as well as the decomposition products 4-6.With 6-chloro-1,3-dimethyluracil (1b) 3h is formed, which in turn photoeliminates benzoyl chloride to give the pyrazolopyrimidine 7.Saponification of 3a gives smoothly 5-benzoyl-1,3-dimethyluracil (photoselective 5-benzoylation). - A new and simple synthesis of 3,6-disubstituted 1,2,4,5-tetrazines from aroylhydrazines is described, employing the system triphenylphosphane/hexachloroethane/triethylamine.