750594-52-6

Basic information

• Product Name: tert-Butyl-{(S)-2-[(2S,5R)-2-isopropyl-5-methyl-cyclohex-(E)-ylidenemethyl]-3,3-dimethyl-butoxy}-dimethyl-silane
• Synonyms: tert-Butyl-{(S)-2-[(2S,5R)-2-isopropyl-5-methyl-cyclohex-(E)-ylidenemethyl]-3,3-dimethyl-butoxy}-dimethyl-silane
• CAS NO: 750594-52-6
• Molecular Weight: 366.703
• Mol File: 750594-52-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tert-Butyl-{(S)-2-[(2S,5R)-2-isopropyl-5-methyl-cyclohex-(E)-ylidenemethyl]-3,3-dimethyl-butoxy}-dimethyl-silane(CAS DataBase Reference)
• NIST Chemistry Reference: tert-Butyl-{(S)-2-[(2S,5R)-2-isopropyl-5-methyl-cyclohex-(E)-ylidenemethyl]-3,3-dimethyl-butoxy}-dimethyl-silane(750594-52-6)
• EPA Substance Registry System: tert-Butyl-{(S)-2-[(2S,5R)-2-isopropyl-5-methyl-cyclohex-(E)-ylidenemethyl]-3,3-dimethyl-butoxy}-dimethyl-silane(750594-52-6)

Safety Data

• Hazardous Substances Data: 750594-52-6(Hazardous Substances Data)

Upstream product

• 750594-48-0 (1R,2S,5R)-2-i-propyl-5-methyl-1-(3-t-butyldimethylsyloxy-1-propen-1-yl)cyclohexan-1-ol 
• 76782-82-6 tert-Butyldimethyl(prop-2-ynyloxy)silane 
• 594-19-4 tert.-butyl lithium 
• 750594-50-4 Carbonic acid (1R,2S,5R)-1-[(E)-3-(tert-butyl-dimethyl-silanyloxy)-propenyl]-2-isopropyl-5-methyl-cyclohexyl ester methyl ester 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 116381-84-1 (E)-1-tert-butyldimethylsilyloxy-3-iodo-2-propene 

Downstream Products

• 750594-70-8 {(S)-1-[(2S,5R)-2-Isopropyl-5-methyl-cyclohex-(E)-ylidenemethyl]-2,2-dimethyl-propyl}-carbamic acid 9H-fluoren-9-ylmethyl ester 
• 750594-60-6 {(S)-1-[(2S,5R)-2-Isopropyl-5-methyl-cyclohex-(E)-ylidenemethyl]-2,2-dimethyl-propyl}-carbamic acid methyl ester 
• 142618-93-7 (R)-(+)-4-tert-butyloxazolidin-2-one 
• 750594-59-3 (S)-2-[(2S,5R)-2-Isopropyl-5-methyl-cyclohex-(E)-ylidenemethyl]-3,3-dimethyl-butyric acid 

Relevant articles and documents

A stereodivergent approach to amino acids, amino alcohols, or oxazolidinones of high enantiomeric purity

(-)-Menthone, an inexpensive chiral auxiliary, was used to prepare both enantiomers of α-amino acids, amino alcohols, or oxazolidinones. The sequence includes the SN2′ displacement by a cuprate reagent and a Curtius rearrangement as key steps.