75104-08-4Relevant articles and documents
FORMATION OF DIALKOXYPHOSPHINYLALKYLIDENE DERIVATIVES OF GALACTITOL BY TRANSACETALATION REACTION
Yanai, Shaul,Halmann, Mordehai,Vofsi, David
, p. 243 - 248 (2007/10/02)
Transacetalation reactions of galactitol with 2,2-dialkoxyethylphosphonates gave the expected 1,3:4,6-diacetal as the minor product, but the major product was a 1,3:4,5 derivative.With a 3,3-diethoxypropylphosphonate, the 1,3:4,6-diacetal became the major product.The influence of the dialkylphosphinyl substituent on the acetal linkage is shown to be stereoelectronic.