75300-18-4Relevant articles and documents
Nucleophilic substitution in the l-nitro-4-chloroanthraquinone by phenolates and thiophenolates
Tabatskaya,Beregovaya,Vlasov
, p. 861 - 866 (2007/10/03)
In reactions of l-nitro-4-chloroanthraquinone with phenolate anions first is chiefly substituted the chlorine atom, whereas by the thiophenolate anion predominantly is replaced the nitro group. The difference in behavior with this substrate of the O- and S-nucleophiles is attributed to the change in the proportion of electrostatic and orbital interaction.