75397-16-9

Basic information

• Product Name: {((R,R)-1,2-bis(phenyl-o-anisoylphosphino)ethane)(MeOH)2}rhodium tetrafluoroborate
• CAS NO: 75397-16-9
• Molecular Weight: 712.271
• Mol File: 75397-16-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: {((R,R)-1,2-bis(phenyl-o-anisoylphosphino)ethane)(MeOH)2}rhodium tetrafluoroborate(CAS DataBase Reference)
• NIST Chemistry Reference: {((R,R)-1,2-bis(phenyl-o-anisoylphosphino)ethane)(MeOH)2}rhodium tetrafluoroborate(75397-16-9)
• EPA Substance Registry System: {((R,R)-1,2-bis(phenyl-o-anisoylphosphino)ethane)(MeOH)2}rhodium tetrafluoroborate(75397-16-9)

Safety Data

• Hazardous Substances Data: 75397-16-9(Hazardous Substances Data)

Upstream product

• 55739-58-7 (Rp,Rp)-1,2-bis[(o-methoxyphenyl)(phenyl)phosphino]ethane 
• 75085-38-0 {((R,R)-1,2-bis(phenyl-o-anisoylphosphino)ethane)(norbornadiene)}rhodium tetrafluoroborate 
• 67-56-1 methanol 

Relevant articles and documents

Oxidative addition of aryl halides to cationic bis(Phosphane)rhodium complexes: Application in C-C bond formation

The oxidative addition of chloro-, bromo-and iodobenzene to the cationic bis(phosphane)rhodium complex [Rh(DIPAMP)(MeOH)2]BF4 was investigated. The resulting complexes were characterized by X-ray analysis and NMR spectro-scopy and ap

Asymmetrie Hydrogenation. Dimerization of Solvate Complexes: Synthesis and Characterization of Dimeric [Rh(DIPAMP)]2+2, a Valuable Catalyst Precursor

The hydrogenation of [Rh(DIPAMP)(NBD)]BF4 (DIPAMP= l,2-bis[(2-methoxyphenyl)(phenylphosphino)]ethane, NBD = 2,5-norbornadiene) in methanol leads not only to the formation of the expected solvate complex [Rh(DIPAMP)(MeOH)2]BF4/s