754-19-8Relevant articles and documents
Deuterium-exchange reaction in a CF3CHBrCl-D2O two-liquid phase system
Ogata, Yukio,Sugihara, Kei-ichi,Sakka, Tetsuo,Iwasaki, Matae
, p. 285 - 292 (1992)
An alkali-catalyzed hydrogen isotope exchange reaction was studied in a CF3CHBrCl-D2O two liquid phase system.The exchange rate was comparable to that in the CHCl3-D2O system previously recognized as the system having the highest exchange rate under alkaline conditions.It was confirmed that CF3CHBrCl was resistant to decomposition caused by alkali.These properties indicate that CF3CHBrCl could be a candidate for a working material in laser hydrogen-isotope separation processes.
Enthalpy of Mixing of Liquid Binary Mixtures with Component Association. The System Dioxolane-Halothane
Francesconi, R.,Lunelli, B.,Comelli, F.
, p. 109 - 118 (2007/10/02)
The mixture halothane-dioxolane was investigated by means of FT-IR to get the pattern of the association reactions.By entering such information together with earlier calorimetric data into the formulae for a model of associated liquid solutions proposed previously, we could evaluate the equilibrium constants and the enthalpy changes of the association reactions, as well as some parameters characteristic of the extended regular solution model.A comparison is made between the results obtained from different implementations of the overall procedure.Solutions / Equilibria / Associations / Dioxolane / Halothane
