75470-72-3

Basic information

• Product Name: 3-p-Tolyl-4-aza-tricyclo[4.3.1.1^3,8]undecane
• CAS NO: 75470-72-3
• Molecular Weight: 241.376
• Mol File: 75470-72-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3-p-Tolyl-4-aza-tricyclo[4.3.1.1^3,8]undecane(CAS DataBase Reference)
• NIST Chemistry Reference: 3-p-Tolyl-4-aza-tricyclo[4.3.1.1^3,8]undecane(75470-72-3)
• EPA Substance Registry System: 3-p-Tolyl-4-aza-tricyclo[4.3.1.1^3,8]undecane(75470-72-3)

Safety Data

• Hazardous Substances Data: 75470-72-3(Hazardous Substances Data)

Upstream product

• 24886-73-5 1-Azidoadamantane 
• 108-88-3 toluene 

Relevant articles and documents

Rearrangement of 1-Azidoadamantane to 3-Aryl-4-azahomoadamantane in the Presence of Aluminum Chloride and Aromatic Substrates

Reaction of 1-azidoadamantane (1) with aromatic substrates in the presence of aluminum chloride at 80 deg C for 1.25 h gave the corresponding 3-aryl-4-azahomoadamantane (2) in >90 percent yield.The reaction of 1 to 2 represents the first report of intermolecular aminoalkylation of aromatics in the benzene series, presumably from an imine intermediate.At 18 deg C, only 3-hydroxy-4-azahomoadamantane is obtained.Addition of water to the reaction system at 80 deg C yielded 1-phenyladamantane (4) as the major product.Mechanistic features are treated.