75474-03-2

Basic information

• Product Name: p-nitrobenzoic acetic anhydride
• Synonyms: p-nitrobenzoic acetic anhydride
• CAS NO: 75474-03-2
• Molecular Weight: 209.158
• Mol File: 75474-03-2.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: p-nitrobenzoic acetic anhydride(CAS DataBase Reference)
• NIST Chemistry Reference: p-nitrobenzoic acetic anhydride(75474-03-2)
• EPA Substance Registry System: p-nitrobenzoic acetic anhydride(75474-03-2)

Safety Data

• Hazardous Substances Data: 75474-03-2(Hazardous Substances Data)

Upstream product

• 902-47-6 p-nitrobenzoic anhydride 
• 64-19-7 acetic acid 
• 15922-01-7 potassium 4-nitrobenzoate 
• 75-36-5 acetyl chloride 
• 127-08-2 potassium acetate 
• 122-04-3 4-nitro-benzoyl chloride 
• 201230-82-2 carbon monoxide 
• 127-09-3 sodium acetate 
• 456-27-9 4-nitrobenzenediazonium tetrafluoroborate 

Downstream Products

• 1131-62-0 1-(3,4-dimethoxyphenyl)ethanone 
• 103-84-4 Acetanilid 
• 902-47-6 p-nitrobenzoic anhydride 
• 108-24-7 acetic anhydride 
• 14687-09-3 2,3,4,6-tetra-O-acetyl-1-O-(p-nitrobenzoyl)-β-D-glucopyranose 
• 604-69-3 β-D-glucose pentaacetate 
• 604-68-2 α-D-glucopyranose peracetylate 

Relevant articles and documents

An efficient and simple procedure for preparation of esters and anhydrides from acid chlorides in the presence of 1,4-diazabicyclo[2.2.2]octane (DABCO) under solvent-free conditions

A manipulatively one-pot and rapid method for the synthesis of aliphatic and aromatic ester and anhydride from acid chloride and alcohol or potassium salt of carboxylic acid under solvent-free conditions is reported. The reaction has been carried out in excellent yield and short reaction time in the presence of 1,4-diazabicyclo[2.2.2]octane (DABCO) under solvent-free conditions.

A facile synthesis of acid anhydrides

A facile synthesis of symmetric and unsymmetric acid anhydrides using phase-transfer catalysis is described. By this method different types of anhydrides can be obtained in high yields under mild conditions even on microscale levels.

NOVEL TRANSFORMATION OF ARENEDIAZONIUM SALTS TO ACID ANHYDRIDES UNDER PALLADIUM CATALYSIS

Palladium catalyzed reaction of arenediazonium salts, carbon monoxide and sodium carboxylates gave mixed anhydrides, wich in turn could be converted to aromatic acid anhydrides in good yields.