75534-18-8Relevant articles and documents
Synthesis and characterization of 1-methyl-1-silaindane and 1-methyl-1-germaindane
Ruddy, Daniel A.,Berry, Donald H.,Nataro, Chip
, p. 169 - 172 (2008)
New synthetic routes to 1-methyl-1-silaindane (1b) and 1-methyl-1-germaindane (1b) were developed and the desired products were obtained in good isolated yield. Compounds 1a and 1b were fully characterized by mass spectroscopy, 1H and 13/
One-pot synthesis of aminoenone via direct reaction of the chloroalkyl enone with NaN3: Rapid access to polycyclic alkaloids
Zhao, Yu-Ming,Gu, Peiming,Tu, Yong-Qiang,Zhang, Hai-Jun,Zhang, Qing-Wei,Fan, Chun-An
supporting information; experimental part, p. 5289 - 5295 (2010/10/19)
(Figure presented) A new one-pot procedure for the preparation of aminoenone from chloroalkyl enone and sodium azide was demonstrated. The structure of the presumed triazoline intermediate in this process was confirmed by X-ray analysis for the first time. As the application of this methodology, the synthesis of polycyclic alkaloid hexahydroapoerysopine (1a) was achieved through an efficient synthetic route.
Lithiophenylalkyllithiums: New dilithium reagents having both sp2- and sp3-hybridised remote carbanionic centres
Yus, Miguel,Ramón, Diego J.,Gómez, Inmaculada
, p. 21 - 31 (2007/10/03)
The reaction of chloro-(2-chloroethyl)benzenes (1), 4-chloro-(3-chloropropyl)benzene (3) or 4-chlorophenyl chloromethyl ether (5) with lithium power using naphthalene as the electron shuttle (8 mol%) in the presence of different carbonyl compounds [Busub