75599-82-5

Basic information

• Product Name: m-(trifluoromethyl)-phenyl vinyl sulfide
• Synonyms: m-(trifluoromethyl)-phenyl vinyl sulfide
• CAS NO: 75599-82-5
• Molecular Weight: 204.216
• Mol File: 75599-82-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: m-(trifluoromethyl)-phenyl vinyl sulfide(CAS DataBase Reference)
• NIST Chemistry Reference: m-(trifluoromethyl)-phenyl vinyl sulfide(75599-82-5)
• EPA Substance Registry System: m-(trifluoromethyl)-phenyl vinyl sulfide(75599-82-5)

Safety Data

• Hazardous Substances Data: 75599-82-5(Hazardous Substances Data)

Upstream product

• 401-78-5 3-bromo-1-trifluoromethylbenzene 
• 33735-40-9 2,2-diphenyl-1,3-oxathiolane 

Relevant articles and documents

Palladium-Catalyzed Synthesis of Aryl Vinyl Sulfides via 1,3-Oxathiolanes As Vinyl Sulfide Surrogates

A nontraditional approach to synthesizing aryl vinyl sulfides is described. 2,2-Diphenyl-1,3-oxathiolane slowly liberates a vinyl sulfide anion under basic conditions. Using a Pd/Xantphos catalyst system to activate a wide range of aryl bromides, this transient sulfide species can be effectively trapped and fed into a traditional Pd0/PdII catalytic cycle. Scope and limitations of the methodology are presented along with significant discussion of a competitive C-S bond activation by this catalyst system.