756491-88-0

Basic information

• Product Name: Cyclohexanecarboxaldehyde, 1-acetyl- (9CI)
• Synonyms: Cyclohexanecarboxaldehyde, 1-acetyl- (9CI)
• CAS NO: 756491-88-0
• Molecular Formula: C₉H₁₄O₂
• Molecular Weight: 154.20626
• Product Categories: ACETYLGROUP;ALDEHYDE;METHYL
• Mol File: 756491-88-0.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Cyclohexanecarboxaldehyde, 1-acetyl- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanecarboxaldehyde, 1-acetyl- (9CI)(756491-88-0)
• EPA Substance Registry System: Cyclohexanecarboxaldehyde, 1-acetyl- (9CI)(756491-88-0)

Safety Data

• Hazardous Substances Data: 756491-88-0(Hazardous Substances Data)

Upstream product

• 16963-29-4 4-(cyclohexylidenemethyl)morpholine 
• 75-36-5 acetyl chloride 

Downstream Products

• 929880-83-1 ethyl 3-[1-(1-trimethylsilanyloxyvinyl)cyclohexyl]acrylate 
• 1426575-56-5 1-[1-(2,2-difluorovinyl)cyclohexyl]ethanone 
• 1629870-91-2 N-{1-[1-(2,2-difluorovinyl)cyclohexyl]ethylidene}-4-methylbenzenesulfonamide 
• 1629871-00-6 3-fluoro-1-methylene-2-[(4-tolyl)sulfonyl]-2-azaspiro[4.5]dec-3-ene 

Relevant articles and documents

Nucleophilic 5- Endo - Trig cyclization of 3,3-difluoroallylic metal enolates and enamides: Facile synthesis of ring-fluorinated dihydroheteroles

Metal enolates and enamides bearing difluoroallylic moieties underwent nucleophilic 5-endo-trig cyclization, a process considered to be disfavored according to Baldwin's rules. Whereas no C-cyclization was observed in these reactions, O- and N-cyclization proceeded exclusively to afford 5-fluorinated 2-alkylidene-2,3-dihydrofurans and -2,3-dihydropyrroles, respectively. Georg Thieme Verlag Stuttgart New York.

SmI2-mediated 3-exo-trig cyclisation of δ-oxo-α, β-unsaturated esters to cyclopropanols and derivatives

In the presence of samarium diiodide and a proton source, δ-oxo-γ,γ-disubstituted-α,β-unsaturated esters of general formula R-CO-C(R′,R′)-CHCH-CO2Bn readily cyclise to trans-cyclopropanol products and/or lactones derived from the cis isomers. F