75717-40-7

Basic information

• Product Name: Benzene, [(1E)-1-octenylthio]-
• CAS NO: 75717-40-7
• Molecular Formula: C14H20S
• Molecular Weight: 220.379
• Mol File: 75717-40-7.mol
• Article Data: 18

Chemical Properties

• CAS DataBase Reference: Benzene, [(1E)-1-octenylthio]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(1E)-1-octenylthio]-(75717-40-7)
• EPA Substance Registry System: Benzene, [(1E)-1-octenylthio]-(75717-40-7)

Safety Data

• Hazardous Substances Data: 75717-40-7(Hazardous Substances Data)

Upstream product

• 13910-16-2 n-octylsulfanylbenzene 
• 42843-49-2 (Z)-1-bromo-1-octene 
• 51751-87-2 (E)-1-bromo-1-octene 
• 17314-33-9 tributyltin phenyl sulfide 
• 30506-39-9 phenyl 1-octyl sulfoxide 
• 629-05-0 n-octyne 
• 882-33-7 diphenyldisulfane 
• 108-98-5 thiophenol 
• 3561-67-9 bis(phenylthio)methane 
• 111-71-7 heptanal 
• 42599-17-7 (E)-1-iodo-1-octene 
• 87514-04-3 (E)-1-phenylsulfanyl-1-trimethylsilyl-1-octene 
• 75280-18-1 1-acetoxy-1-phenylthiooctane 
• 121410-98-8 O-<1,1-bis(phenylthio)methylheptyl> S-methyl dithiocarbonate 

Downstream Products

• 98750-72-2 (1,2-Dichloro-octylsulfanyl)-benzene 

Relevant articles and documents

Rhodium-catalyzed hydrothiolation of alkynes with thiols for construction of sulfur-containing π-conjugated systems

To synthesize sulfur-containing π-conjugated polymers, reaction conditions for rhodium-catalyzed hydrothiolation of terminal alkynes with arenethiols are optimized in detail. Under the optimized conditions, rhodium-catalyzed hydrothiolation of terminal al

Heterogeneous hydrothiolation of alkynes with thiols catalyzed by diphosphino-functionalized MCM-41 anchored rhodium complex

A novel diphosphino-functionalized MCM-41 anchored rhodium complex [MCM-41-2P-RhCl(PPh3)] was conveniently synthesized by the reaction of diphosphino-functionalized MCM-41 (MCM-41-2P) with RhCl(PPh3) 3. It was found that this rhodium complex is an efficient catalyst for the hydrothiolation of terminal alkynes with thiols and can be recovered and recycled by a simple filtration of the reaction solution and used for at least ten consecutive trials without any decreases in activity.

Reductive addition of the benzenethiyl radical to alkynes by amine-mediated single electron transfer reaction to diphenyl disulfide

Hydrothiolation of alkynes proceeds with diphenyl disulfide and tripropylamine. Amine-mediated single electron transfer to diphenyl disulfide can be proposed for the reaction mechanism. Applications of the method to radical cyclizations of eneyne compound