757893-62-2

Basic information

• Product Name: 3,5-dideuterio-4-bromoaniline
• Synonyms: 3,5-dideuterio-4-bromoaniline
• CAS NO: 757893-62-2
• Molecular Weight: 174.008
• Mol File: 757893-62-2.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 3,5-dideuterio-4-bromoaniline(CAS DataBase Reference)
• NIST Chemistry Reference: 3,5-dideuterio-4-bromoaniline(757893-62-2)
• EPA Substance Registry System: 3,5-dideuterio-4-bromoaniline(757893-62-2)

Safety Data

• Hazardous Substances Data: 757893-62-2(Hazardous Substances Data)

Upstream product

• 106-40-1 4-bromo-aniline 
• 624-19-1 4-bromoaniline hydrochloride 

Downstream Products

• 84369-43-7 tris(3,4,5-trideutero-phenyl)phosphine 
• 1221821-24-4 tetra(3,5-dideutero-phenyl)phosphonium bromide 
• 1221821-25-5 tetra(3,4,5-trideutero-phenyl)phosphonium bromide 
• 1221821-23-3 tris(3,5-dideutero-phenyl)phosphine 
• 6120-98-5 3,5,3',5'-tetradeuterio-biphenyl 
• 7291-07-8 1-bromo-3,5-dideuteriobenzene 
• 37960-84-2 [3,5-D₂]benzoic acid 

Relevant articles and documents

Rhodium-Catalyzed meta-Selective C?H Carboxylation Reaction of 1,1-Diarylethylenes via Hydrorhodation-Rhodium Migration

A meta-selective C?H carboxylation reaction of 1,1-diarylethylene derivatives with CO2 by using a rhodium catalyst with NaOiPr as a stoichiometric reductant has been achieved. Together with hydrogenation of the ethylene moiety, a carboxyl group was introduced to the meta-position of the aryl ring with high selectivity over the ortho-positions. Experimental and computational mechanistic studies indicate that this carboxylation reaction proceeds via hydrorhodation on the ethylene moiety, followed by 1,4-rhodium migration and successive 1,2-rhodium migration on the aryl ring. The use of a bulky phosphine ligand seems to be the key to this unusual aryl-to-aryl 1,2-rhodium shift.

Parallel NMR based on solution magnetic-susceptibility differences. Application to isotopic effects on self-diffusion

Different susceptibility NMR line shifts can be induced in distinct liquid solutions by dissolving different concentrations of complexes of paramagnetic lanthanide Ln3+ ions. We show how these solutions, put in capillaries, can be simultaneousl

A Study of Gaseous Benzenium and Toluenium Ions generated from 1,4-Dihydro- and 1-Methyl-1,4-dihydro-benzoic Acids

Gaseous benzenium C6H7(1+) (1) and toluenium C7H9(1+) (2) ions have been generated by mass spectrometric loss of .CO2H from the corresponding 1,4-dihydrobenzoic acids (3) and (4), and their fragmentations after ca. 10 μs have been investigated by means of mass-analysed ion kinetic energy (MIKE) spectrometry of some 2H and 13C labelled analogues.Metastable C6H7(1+) ions eliminate H2 after proton randomization, whereas metastable C7H9(1+) ions expel both H2 and CH4 after incomplete proton equilibration.In particular, 40percent of C7H9(1+) ions randomize all their carbon and hydrogen atoms prior to loss of CH4, and 60percent of C7H9(1+) ions lose the original methyl group along with a hydrogen atom from the (proton-equilibrated) benzenium ring, accompanied by a slow and incomplete exchange between the hydrogen atoms of the ring and the methyl group.It is suggested that loss of both CH4 and H2 occur via the (ipso-)toluenium ion (2).The role of a non-classical C7H9(1+) isomer, phenylmethonium ion (6), is discussed since striking similarities are found compared * adducts from ion-molecule reactions described in the literature.