7583-78-0 Usage
Chemical structure
Bicyclic structure containing a benzene ring and an oxepane ring
Physical state
White, crystalline solid
Molecular weight
214.3 g/mol
Applications
Potential use in organic synthesis as a building block for the preparation of various pharmacologically active compounds
Safety
Important to handle with care due to potential health hazards
Laboratory precautions
Appropriate safety measures should be taken when working with 1-benzyl-7-oxabicyclo[4.1.0]heptane in a laboratory setting
Synthetic importance
Versatile compound with significant synthetic applications
Check Digit Verification of cas no
The CAS Registry Mumber 7583-78-0 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 7,5,8 and 3 respectively; the second part has 2 digits, 7 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 7583-78:
(6*7)+(5*5)+(4*8)+(3*3)+(2*7)+(1*8)=130
130 % 10 = 0
So 7583-78-0 is a valid CAS Registry Number.
InChI:InChI=1/C13H16O/c1-2-6-11(7-3-1)10-13-9-5-4-8-12(13)14-13/h1-3,6-7,12H,4-5,8-10H2
7583-78-0Relevant articles and documents
Enantioselective protonation of samarium enolates derived from α- heterosubstituted ketones and lactone by SmI2-mediated reduction
Nakamura, Yutaka,Takeuchi, Seiji,Ohgo, Yoshiaki,Yamaoka, Makoto,Yoshida, Akihiro,Mikami, Koichi
, p. 4595 - 4620 (2007/10/03)
SmI2-mediated reductive cleavage of α-heterosubstituents of α-alkyl or α-aryl ketones and lactone gave the corresponding 'thermodynamic samarium enolates'. Enantioselective protonation of the samarium enolates with C2- symmetric chiral diols afforded the corresponding ketones and lactone in moderate to high enantioselectivities.