75870-97-2

Basic information

• Product Name: Benzoyl fluoride, 4-chloro-2-methyl- (9CI)
• Synonyms: Benzoyl fluoride, 4-chloro-2-methyl- (9CI)
• CAS NO: 75870-97-2
• Molecular Formula: C₈H₆ClFO
• Molecular Weight: 172.5840432
• Product Categories: ACIDHALIDE
• Mol File: 75870-97-2.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Benzoyl fluoride, 4-chloro-2-methyl- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoyl fluoride, 4-chloro-2-methyl- (9CI)(75870-97-2)
• EPA Substance Registry System: Benzoyl fluoride, 4-chloro-2-methyl- (9CI)(75870-97-2)

Safety Data

• Hazardous Substances Data: 75870-97-2(Hazardous Substances Data)

Upstream product

• 7499-07-2 4-chloro-2-methylbenzoic acid 
• 21900-44-7 4-chloro-2-methylbenzoyl chloride 

Relevant articles and documents

N-Heterocyclic Carbene Catalyzed Photoenolization/Diels–Alder Reaction of Acid Fluorides

The combination of light activation and N-heterocyclic carbene (NHC) organocatalysis has enabled the use of acid fluorides as substrates in a UVA-light-mediated photochemical transformation previously observed only with aromatic aldehydes and ketones. Stoichiometric studies and TD-DFT calculations support a mechanism involving the photoactivation of an ortho-toluoyl azolium intermediate, which exhibits “ketone-like” photochemical reactivity under UVA irradiation. Using this photo-NHC catalysis approach, a novel photoenolization/Diels–Alder (PEDA) process was developed that leads to diverse isochroman-1-one derivatives.