75879-01-5

Basic information

• Product Name: (-)-1,2:5,6-di-O-cyclohexylidene-D-glucofuranosyl 3-phenylpropenoate
• CAS NO: 75879-01-5
• Molecular Weight: 470.563
• Mol File: 75879-01-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (-)-1,2:5,6-di-O-cyclohexylidene-D-glucofuranosyl 3-phenylpropenoate(CAS DataBase Reference)
• NIST Chemistry Reference: (-)-1,2:5,6-di-O-cyclohexylidene-D-glucofuranosyl 3-phenylpropenoate(75879-01-5)
• EPA Substance Registry System: (-)-1,2:5,6-di-O-cyclohexylidene-D-glucofuranosyl 3-phenylpropenoate(75879-01-5)

Safety Data

• Hazardous Substances Data: 75879-01-5(Hazardous Substances Data)

Upstream product

• 23397-76-4 1,2:5,6-di-O-cyclohexylidene-α-D-glucofuranose 
• 102-92-1 Cinnamoyl chloride 

Relevant articles and documents

Reaction of Chiral Lithium Diorganocopper Reagents, LiRR*Cu, with α,β-Unsaturated Esters of Chiral Alcohols

Conjugate addition of organometallic reagents to chiral esters of trans-3-phenyl-2-propenoic or trans-2-butenoic acid has been studied.The reagents were PhMgBr, LiPh2Cu, LiMe2Cu, LiMeR*Cu, and LiPhR*Cu.The chiral ligand R* was the 2-(1-dimethylaminoethyl)phenyl group.The assymmetric induction varied between 0.3 and 49percent and was in some cases improved by the presence of the R* ligand.The influence of substituents on the β-carbon of the α,β-unsaturated esters on the stereochemical course of the reaction is related to their coordination ability.The directing effects of the chiral ester functions are discussed.