75898-42-9

Basic information

• Product Name: Benzenepropanoic acid, a-bromo-, 1,1-dimethylethyl ester
• CAS NO: 75898-42-9
• Molecular Formula: C13H17BrO2
• Molecular Weight: 285.181
• Mol File: 75898-42-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzenepropanoic acid, a-bromo-, 1,1-dimethylethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenepropanoic acid, a-bromo-, 1,1-dimethylethyl ester(75898-42-9)
• EPA Substance Registry System: Benzenepropanoic acid, a-bromo-, 1,1-dimethylethyl ester(75898-42-9)

Safety Data

• Hazardous Substances Data: 75898-42-9(Hazardous Substances Data)

Upstream product

• 540-88-5 acetic acid tert-butyl ester 
• 16503-53-0 2-bromo-3-phenylpropanoic acid 
• 87769-52-6 tert-butyl 2-benzylacetoacetate 

Downstream Products

• 1010445-86-9 tert-butyl 3-(1-tert-butoxycarbonyl-2-phenylethyl)-5-chloro-2-oxo-2,3-dihydrobenzimidazole-1-carboxylate 
• 109309-90-2 (S)-N-benzoylphenylalanine tert-butyl ester 
• 16367-71-8 t-butyl (RS)-phenylalaninate 
• 81852-06-4 (2S,3S,4R,5R)-2-Methyl-3,5-diphenyl-pyrrolidine-2,4-dicarboxylic acid 2-benzyl ester 4-tert-butyl ester 
• 1035804-39-7 (2S,3S)-tert-Butyl 3-amino-2-benzyl-3-phenylpropanoate 
• 14990-09-1 tert-butyl cinnamate 
• 118387-86-3 2-((S)-2-Amino-3-phenyl-propylsulfanyl)-3-phenyl-propionic acid tert-butyl ester 
• 106377-74-6 2-Azido-3-phenyl-propionsaeure-tert-butylester 

Relevant articles and documents

Multiple Absolute Stereocontrol in Cascade Lactone Formation via Dynamic Kinetic Resolution Driven by the Asymmetric Transfer Hydrogenation of Keto Acids with Oxo-Tethered Ruthenium Catalysts

A straightforward asymmetric construction of chiral fused γ- and δ-lactones containing multiple contiguous stereocenters was successfully developed by either (1) the dynamic kinetic resolution-asymmetric transfer hydrogenation (DKR-ATH) reaction using oxo

One-pot synthesis of α-bromoesters and ketones from β-ketoesters and diketones using supported reagents system

A simple and efficient method has been developed for the synthesis of α-bromoesters and ketones from β-ketoesters and diketones in one pot using a supported reagents system, CuBr2/Al2O 3-Na2CO3/Al2O3, in which β-ketoester reacts first with CuBr2/Al2O3 and the product, α-bromo-β-ketoester, reacts with Na 2CO3/Al2O3 to give the final product, α-bromoesters in good yields.